Structure-Property Relationships in Thermoplastic-Apparent Interpenatrating Polymer Networks Based on Crystallizable Polyurethane and Styrene-Acrylic Acid Copolymer

摘要

Structure-property relationships in thermoplastic-apparent interpenetrating polymer networks (t-AIPNs), prepared by mechanical blending in a common solvent of crystallizable polyurethane (CPU) and styrene/acrylic acid random copolymer (S/AA), were investigated by means of wide -angle and small-anle X-ray scattering (WAXS and SAXS), dynamic mechanical analysis (DMA), thermally stimulated depolarization currents (TSDC) techniques, dielectric relaxation spectroscopy (DRS), and density, water uptake, deformation, and strength characteristics measurements. Several mechanical and dielectric relaxations of the pure components were characterized, and the effects thereupon induced by blending were followed. The two components show weak affinity to each other. The t-AIPNs can be classified into two groups with high and low contents of CPU, showing essentially the behavior of CPU and of S/AA, respectively. On the other hand, deviataions from additivity in several properties indicate interactions between the two components, caused by the formation of H-bonds between their functional groups, and resulting i npartial miscibility. In addition, signficant changes are observed on some properties of the t-AIPNs on addition of small amounts of eithre of the components.