Graft Polymerization of Methyl Methacrylate onto Radiaton-Peroxidized Ultrahigh Molecular Weight Polyethylene in the Presence of Metallic Salt and Acid

摘要

Using a radiation peroxide grafting technique, a ultrahigh molelcular weight polyethylene (UHMWPE) stored at room temperature for 10 days after irradiation in air was graft copolymerized with methyl methacrylate (MMA) in the presence of metallic salt and acid. The MMA-grafted UHMWPE samples were analyzed by measuring Furier transform infrared spectroscopy in attenated total reflectance (FTIR-ATR) and by electron spectroscopy for chemical analysis (ESCA). The 1,1-diphenyl-2-picrylhydrzyl (DPPH) technique was utilized to evaluate the concentration of peroxide formed in the peroxidized UHMWPE samples by counting the quantity of DPPH consumed from the reaction of peroixide radicals with DPPH. It was shown that the inclusion of an FsSO_4 centre dot 7H_2O and sulfuric acid in MMA grafting solutions was extremely beneficial and led to a most unusual synergistic effect in the radiation-peroxidized grafting.