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首页> 外文期刊>Journal of Applied Polymer Science >Polyblend system sof polyurethane (AU) and Ethylene acrylic elastomer(vamac)using the sulfur cure systems
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Polyblend system sof polyurethane (AU) and Ethylene acrylic elastomer(vamac)using the sulfur cure systems

机译:使用硫磺硫化体系的聚氨酯(AU)和乙烯丙烯酸弹性体(vamac)的共混体系

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摘要

Blends of polyurethane (Vibrathane-5008, Uniroyal Co., USA) and ethylene acrylic elastomer (vamac B-124, du Pont, USA) prepared through three different blending techniques have been studied over the entire composition range. The process-ability and the aging properties of the polyurethane elastomer were improved as a result of blending with ethylene acrylic elastomer. IR spectral analysis of the (50:50) blend of the two elastomers, without any curatives, suggested that the interchain crosslinking reaction occurred between the two elastomers phases on heat treatment. The thermal stability of the blends also improved on heat treatment, before addition of curatives. Phase morphological study revealed that the extractability of the single phase by solvent was also restricted on preheating the preblends, probably due to the interchain crosslinking.
机译:在整个组成范围内,已经研究了通过三种不同的混合技术制备的聚氨酯(Vibrathane-5008,美国Uniroyal公司)和乙烯丙烯酸弹性体(vamac B-124,美国杜邦)的共混物。通过与乙烯丙烯酸类弹性体共混,可改善聚氨酯弹性体的加工性能和老化性能。没有任何固化剂的两种弹性体(50:50)共混物的红外光谱分析表明,热处理时两种弹性体相之间发生链间交联反应。在添加固化剂之前,热处理后共混物的热稳定性也得到改善。相形态学研究表明,溶剂对单相的萃取能力在预热预混物中也受到限制,这可能是由于链间交联所致。

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