Ionic liquids with an anion of N-lauroyl sarcosinate in membranes of ion-selective electrode

摘要

The study considers solubility in water, extractivity, and electrode properties of ionic liquids (IL), lauroyl tetrahexylammonium (THALS) and tetraoctylammonium lauroyl sarcosinate (TOALS). The values of solubility, found by potentiometry using ion-selective membranes of PVC-electrodes (ISE) have appeared to be 3.0 ± 0.4 mM and 0.011 ± 0.005 mM, for THALS and TOALS, respectively. Both IL quantitatively recover nitrophenol (99.9%) into chloroform from aqueous solutions in the pH range from 2 to 12. The application of IL as the active components of PVC-ISE enables the determination of lauroyl sarcosinate anion in the concentration range 1 × 10 ~(-2) -1 × 10 ~(-4) M for THALS and 1 × 10 ~-2-1 × 10 ~(-5) M for TOALS and the determination of mononitrophenols, 2,4-dinitrophenols and picrates (1 × 10 ~(-2) M-1 × 10 ~(-5) M). A solid-state sensor based on screen-printed electrode modified by TOALS IL has been proposed. The electrode has been used for the determination of 4-nitrophenol in the concentration range 1 × 10 ~(-2)-1 × 10 ~(-5) M, the operational stability of the electrode is 10 days.