NUCLEOPHILIC PHOSPHINE-CATALYZEDIODOCYCLIZATION OF ISOPRENOIDS BEARING AN OXYGEN TERMINAL GROUP

Akira Sakakura; Gakujun Shomi; Atsushi Ukai

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NUCLEOPHILIC PHOSPHINE-CATALYZEDIODOCYCLIZATION OF ISOPRENOIDS BEARING AN OXYGEN TERMINAL GROUP

机译：带有氧末端基团的异戊二烯的核生化膦催化过氧化氢化

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The nucleophilic phosphine-catalyzed diastereoselective iodocyclization of linear isoprenoids bearing an oxygen terminal group was investigated. TBDMS ether of homogeraniol and TBDMS ester of homogeranic acid were successfully converted to the corresponding iodopolycyclic products in the presence of a catalytic amount of triphenylphosphine with complete diastereoselectivity.

机译：研究了带有氧末端基团的线性类异戊二烯的亲核膦催化的非对映选择性碘环化。在催化量的三苯膦的存在下，具有完全非对映选择性的高香叶醇的TBDMS醚和高香叶酸的TBDMS酯已成功转化为相应的碘多环产物。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2010年第1期|共7页
作者
Akira Sakakura; Gakujun Shomi; Atsushi Ukai;
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中图分类化学;
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1. NUCLEOPHILIC PHOSPHINE-CATALYZEDIODOCYCLIZATION OF ISOPRENOIDS BEARING AN OXYGEN TERMINAL GROUP [J] . Akira Sakakura, Gakujun Shomi, Atsushi Ukai Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2010,第1期

机译：带有氧末端基团的异戊二烯的核生化膦催化过氧化氢化
2. Nature of the Nucleophilic Oxygenation Reagent Is Key to Acid-Free Gold-Catalyzed Conversion of Terminal and Internal Alkynes to 1,2-Dicarbonyls [J] . Dubovtsev Alexey Yu., Shcherbakov Nikolay V., Darin Dmitry V., The Journal of Organic Chemistry . 2020,第2期

机译：亲核氧化试剂的性质是终端和内炔醇的无酸金催化转化为1,2-二羰基的关键
3. Iron-Catalyzed Acylation-Oxygenation of Terminal Alkenes for the Synthesis of Dihydrofurans Bearing a Quaternary Carbon [J] . Lv Leiyang, Lu Shenglin, Guo Qiaoxia, The Journal of Organic Chemistry . 2015,第1期

机译：铁催化末端烯烃的酰化氧合反应合成带有季碳的二氢呋喃
4. Carbonyl vs. N-Terminal vs. Side-Chain Directed Nucleophilic Attacks in Peptide Collision-Induced Dissociation [C] . Shen Zou, Warren K. Mino, Xian Chen, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2010

机译：羰基与N-末端对肽碰撞诱导解离的侧链导向核心攻击
5. Synthesis of cyclic ketene nitrogen,oxygen-acetals and their reactions with isocyanates and isothiocyanates. Nucleophilic substitutions in ionic liquids. [D] . Liu, Zhuqing. 2003

机译：环状烯酮氮，氧-乙缩醛的合成及其与异氰酸酯和异硫氰酸酯的反应。离子液体中的亲核取代。
6. Posttranslational modification of Ha-ras p21 by farnesyl versus geranylgeranyl isoprenoids is determined by the COOH-terminal amino acid. [O] . B T Kinsella, R A Erdman, W A Maltese 1991

机译：法呢基相对于香叶基香叶基类异戊二烯对Ha-ras p21的翻译后修饰取决于COOH末端氨基酸。
7. Nature of the Nucleophilic Oxygenation Reagent Is Key to Acid-Free Gold-Catalyzed Conversion of Terminal and Internal Alkynes to 1,2Dicarbonyls [O] . -1

机译：亲核氧化试剂的性质是终端和内炔醇的无酸金催化转化至1,2dicarbonyls的关键

NUCLEOPHILIC PHOSPHINE-CATALYZEDIODOCYCLIZATION OF ISOPRENOIDS BEARING AN OXYGEN TERMINAL GROUP

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