STEREOSELECTIVE SYNTHESIS OF 2,3,5-TRISUBSTITUTED PYRROLIDINES USING METATHESIS-DERIVED β-AMINOALLYLSILANES

Alison D. McEIhinney; Stephen P. Marsden

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STEREOSELECTIVE SYNTHESIS OF 2,3,5-TRISUBSTITUTED PYRROLIDINES USING METATHESIS-DERIVED β-AMINOALLYLSILANES

机译：介导衍生的β-酰胺基丙二烯键立体合成2,3,5-三取代的吡咯烷酮

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Amine-functionalised allylsilanes, readily prepared by olefin cross metathesis of protected homoallylamines with allyltrimethylsilane, undergo stereoselective condensation with aldehydes to yield trisubstituted pyrrolidines.

机译：胺官能化的烯丙基硅烷很容易通过烯烃与被保护的烯丙基胺与烯丙基三甲基硅烷的交叉复分解反应制得，与醛进行立体选择性缩合，生成三取代的吡咯烷。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2009年第1期| 共6页
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Alison D. McEIhinney; Stephen P. Marsden;
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1. STEREOSELECTIVE SYNTHESIS OF 2,3,5-TRISUBSTITUTED PYRROLIDINES USING METATHESIS-DERIVED β-AMINOALLYLSILANES [J] . Alison D. McEIhinney, Stephen P. Marsden Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2009 ,第1期

机译：介导衍生的β-酰胺基丙二烯键立体合成2,3,5-三取代的吡咯烷酮
2. Stereoselective Synthesis of 2,3,5-Trisubstituted Tetrahydrofurans Initiated by a Titanium-BINOLate-Catalyzed Vinylogous Aldol Reaction [J] . Hoffmeyer Patrick, Schneider Christoph The Journal of Organic Chemistry . 2019 ,第2期

机译：由钛 - 硼酸钛催化的乙烯基芳基反应引发的2,3,5-三取代的四氢呋喃的立体选择性合成
3. Kinetic and thermodynamic control in the cyclization via thiiranium ions. Stereoselective synthesis of a 2,3,5-trisubstituted tetrahydropyran ring. [J] . Gruttadauria M., Noto R. Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2001 ,第3期

机译：通过th离子在环化过程中的动力学和热力学控制。 2,3,5-三取代的四氢吡喃环的立体选择性合成。
4. Microwave synthesis of 2,3,5-trisubstituted-1,3-imidazolidin-4-ones bearing 1,3,4-oxadiazole moiety and preliminary evaluation of their antibacterial activity [C] . Zeid Hassan Abood, Hayder Raheem Ali, Hussein Ali Qabel International Conference on Applied Science and Technology . 2019

机译：微波合成2,3,5-三取代-1,3-咪唑烷-4-轴承1,3,4-氧代唑部分，对其抗菌活性的初步评估
5. The regio- and stereoselective synthesis of 2,3,5-trisubstituted tetrahydrofurans via cyclization of epoxy diols and total synthesis of the proposed structure of mucoxin [D] . Narayan, Radha Sridhar 2004

机译：通过环氧二醇的环化和选择性合成粘液毒素的区域和立体选择性合成2,3,5-三取代的四氢呋喃
6. Stereoselective Synthesis of Trisubstituted Vinyl Bromides by Addition of Alkynes to Oxocarbenium Ions [O] . Andrew R. Ehle, Melissa G. Morris, Bryan D. Klebon, -1

机译：通过将炔烃加到氧碳鎓离子上的立体选择性合成三取代乙烯基溴化物
7. AgOTf-catalyzed cyclization of enynals or enynones with amines: an efficient synthesis of 1,2,4-trisubstituted pyrroles and 2,3,5-trisubstituted furans [O] . Wan-Li Chen, Jiao Li, Ying-Hong Zhu, 2011

机译：agOTf催化的烯醛或烯炔与胺的环化：1,2,4-三取代吡咯和2,3,5-三取代呋喃的有效合成
8. Enolboration 7. Dicyclohexyliodoborane, a Highly Stereoselective Reagent For theEnolboration Of Tertiary Amides. Effects of Solvent And Aldolization Temperature on Stereochemistry Achieving the Stereoselective Synthesis of Either Syn or Anti Aldols [R] . Ganesan, K., Brown, H. C. 1994

机译：配合7.二环己基碘硼烷，一种高立体选择性试剂，用于叔酰胺的合成。溶剂和醛醇化温度对立体化学实现syn或anti aldols立体选择性合成的影响

STEREOSELECTIVE SYNTHESIS OF 2,3,5-TRISUBSTITUTED PYRROLIDINES USING METATHESIS-DERIVED β-AMINOALLYLSILANES

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