THE DAKIN-WEST REACTION OF N-ACYLPROLINES IN THE PRESENCE OF INORGANIC BASES: UNEXPECTED FORMATION OF ENOL ESTERS

Momoko Saeki; Yuri Hagimoto; Hidemitsu Uno

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >THE DAKIN-WEST REACTION OF N-ACYLPROLINES IN THE PRESENCE OF INORGANIC BASES: UNEXPECTED FORMATION OF ENOL ESTERS

【24h】

THE DAKIN-WEST REACTION OF N-ACYLPROLINES IN THE PRESENCE OF INORGANIC BASES: UNEXPECTED FORMATION OF ENOL ESTERS

机译：无机碱存在下N-酰基脯氨酸的达金-韦斯特反应：烯醇酯的意外形成

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

团队文献服务 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A novel transformation of N-acylprolines (1) to enol esters (2) was realized by utilizing chlorodifluoroacetic or trifluoroacetic anhydrides in the presence of inorganic bases, in which probable intermediates were mesoionic 1,3-oxazolium-5-olates. The structure of the enol ester (2a) was determined by single crystal X-ray analysis.

机译：通过在无机碱存在下利用氯二氟乙酸酐或三氟乙酸酐实现了N-酰基脯氨酸（1）向烯醇酯（2）的新型转化，其中可能的中间体是中离子的1,3-恶唑鎓5-油酸酯。通过单晶X射线分析确定烯醇酯（2a）的结构。

著录项

来源
《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2009年第1期| 共10页
作者
Momoko Saeki; Yuri Hagimoto; Hidemitsu Uno;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学工业 ;
关键词

相似文献

外文文献
中文文献
专利

1. THE DAKIN-WEST REACTION OF N-ACYLPROLINES IN THE PRESENCE OF INORGANIC BASES: UNEXPECTED FORMATION OF ENOL ESTERS [J] . Momoko Saeki, Yuri Hagimoto, Hidemitsu Uno Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2009 ,第1期

机译：无机碱存在下N-酰基脯氨酸的达金-韦斯特反应：烯醇酯的意外形成
2. Chalcone and cinnamate synthesis via one-pot enol silane formation-Mukaiyama aldol reactions of ketones and acetate esters [J] . Downey C. Wade, Glist Hadleigh M., Takashima Anna, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2018 ,第32期

机译：Chalcone和肉桂醛合成通过单壶烯醇硅烷形成-Mukaiyama aldol酮和醋酸酯的反应
3. Gold(I)-Catalyzed Divergence in the Preparation of Bicyclic Enol Esters: From Exclusively [3C+2C]-Cycloaddition Reactions to Exclusive Formation of Vinylcyclopropanes [J] . Ryan C. Conyers, BenjaminW. Gung Chemistry: A European journal . 2013 ,第2期

机译：金（I）催化的双环烯醇酯的制备中的发散：从独家[3C + 2C]-环加成反应到乙烯基环丙烷的独家形成
4. Reaction of Olive Oil with Iodine in the Presence of Ethanol:Formation of the Iodoethoxylated Fatty Acids Ethyl Ester [C] . Fuzuki Shimizu, Nao Ikegami, Hor Seanghai 日本化学会春季年会 . 2020

机译：橄榄油与碘在乙醇存在下的反应：碘乙氧基化脂肪酸的形成乙酯
5. Copper-catalyzed cross-coupling reactions of organotrifluoroborate salts and organoboronic acids: Formation of enol esters and sulfones [D] . Huang, Fang 2007

机译：铜催化的有机三氟硼酸盐和有机硼酸的交叉偶联反应：烯醇酯和砜的形成
6. Scope and Mechanistic Investigations on the Solvent-Controlled Regio- and Stereoselective Formation of Enol Esters from the Ruthenium-Catalyzed Coupling Reaction of Terminal Alkynes and Carboxylic Acids [O] . Chae S. Yi, Ruili Gao -1

机译：从终端炔烃和羧酸的钌催化偶联反应烯醇酯的溶剂控制的区域选择性和立体选择性合成范围和机理的调查
7. The Formation of Acetylenic Bond by the Elimination Reaction of Some Enol-esters. I. Syntheses of Enol-esters [O] . Masazumi Nakagawa, Gen Nakaminami, Fumio Ogura, 1962

机译：通过消除一些烯醇酯的消除反应形成乙炔键。 I.烯醇酯的合成
8. Reactions of Singlet Oxygen with Enol Esters [R] . Wilson, S. L., Schuster, G. B. 1985

机译：单线态氧与烯醇酯的反应

THE DAKIN-WEST REACTION OF N-ACYLPROLINES IN THE PRESENCE OF INORGANIC BASES: UNEXPECTED FORMATION OF ENOL ESTERS

摘要

著录项

相似文献

相关主题

期刊订阅