STEREOSELECTIVE SYNTHESIS OF TRANS-3a-ARYLOCTAHYDROINDOLES USING CYCLIZATION OF N-VINYLIC alpha-(METHYLTHIO)ACETAMIDES

Miho Saito; Jun-ichi Matsuo; Masahiko Uchiyama

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STEREOSELECTIVE SYNTHESIS OF TRANS-3a-ARYLOCTAHYDROINDOLES USING CYCLIZATION OF N-VINYLIC alpha-(METHYLTHIO)ACETAMIDES

机译：N-乙烯基α-（甲基硫代）乙酰胺的循环立体合成反式-3a-芳基吲哚

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Treatment of N-(2-arylcyclohex-1-enyl)-alpha-(methylthio)acetamide with NCS underwent cyclization to give 3a-arylhexahydroindol-2-one,which was stereoselectively converted into trans-3a-aryloctahydroindole.

机译：用NCS处理N-（2-芳基环己-1-烯基）-α-（甲硫基）乙酰胺，进行环化反应，得到3a-芳基六氢吲哚-2-酮，将其立体选择性地转化为反式-3a-芳基氢化吲哚。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2006年第1期|共4页
作者
Miho Saito; Jun-ichi Matsuo; Masahiko Uchiyama;
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正文语种 eng
中图分类杂环化合物;
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1. STEREOSELECTIVE SYNTHESIS OF TRANS-3a-ARYLOCTAHYDROINDOLES USING CYCLIZATION OF N-VINYLIC alpha-(METHYLTHIO)ACETAMIDES [J] . Miho Saito, Jun-ichi Matsuo, Masahiko Uchiyama Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2006,第1期

机译：N-乙烯基α-（甲基硫代）乙酰胺的循环立体合成反式-3a-芳基吲哚
2. Bimolecular homolytic substitution (S(H)2) reactions with hydrogen atoms. Time-resolved electron spin resonance detection in the pulse radiolysis of alpha-(methylthio)acetamide [J] . Wisniowski P, Bobrowski K, Carmichael I, Journal of the American Chemical Society . 2004,第44期

机译：与氢原子的双分子均溶取代（S（H）2）反应。 α-（甲硫基）乙酰胺脉冲辐解中的时间分辨电子自旋共振检测
3. Trimethylsilyl chloride assisted conjugate addition-elimination of organocopper reagents to 2-bis(methylthio) nitroethylene: An efficient and highly stereoselective synthesis of 2-methylthio-2-alkyl/aryl-1-nitroethylenes and their application for syn [J] . Terang N., Ila H., Junjappa H., Tetrahedron . 1998,第42期

机译：三甲基氯硅烷辅助的有机铜试剂与2-双（甲硫基）硝基乙烯的共轭加成消除反应：2-甲硫基-2-烷基/芳基-1-硝基乙烯的高效且立体选择性高的合成及其在合成中的应用
4. Thiolate-Initiated Synthesis of Dibenzothiophenes from 2,2’-Bis(methylthio)-1,1’-Biphenyl via the Cleavage of Two Carbon-Sulfur Bonds [C] . Yoshihiro Masuya, Yuki Kawashimna, Naoto Chatani 日本化学会春季年会講演予稿集 . 2018

机译：通过两种碳硫键的切割，从2,2'-BIS（甲硫噻吩）-1,1'-联苯的硫醇酸酯的合成二苯甲苯烯酮
5. Efforts towards the total synthesis of vinigrol, stereoselective synthesis of carbocycles and gold-catalyzed benzannulation. [D] . Grise-Bard, Christiane. 2009

机译：努力实现长春总酚的全合成，碳环化合物的立体选择性合成和金催化的苯环化。
6. Direct Synthesis of Azaheterocycles from N-Aryl/Vinyl Amides. Synthesis of 4-(Methylthio)-2-phenylquinazoline and 4-(4-Methoxyphenyl)-2-phenylquinoline [O] . Omar K. Ahmad, Jonathan William Medley, Alexis Coste, -1

机译：从N-芳基/乙烯基酰胺氮杂杂环的直接合成。合成4-（甲硫基）-2-苯基和4-（4-甲氧基苯基）-2-苯基喹啉
7. Stereoselective Synthesis of Trans-3a-Aryloctahydroindoles Using Cyclization of N-Vinylic a-(Methylthio)acetamides [O] . Hiroyuki Ishibashi, Miho Saito, Jun-ichi Matsuo, 2006

机译：使用N-乙烯基A-（甲硫基）乙酰胺环化的Trans-3a-芳基-1吲哚吲哚的立体选择性合成

STEREOSELECTIVE SYNTHESIS OF TRANS-3a-ARYLOCTAHYDROINDOLES USING CYCLIZATION OF N-VINYLIC alpha-(METHYLTHIO)ACETAMIDES

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