ENANTIOSELECTIVE CONJUGATE ADDITION OF ORGANOMETALLIC REAGENTS TOCYCLOALKENONES BY THE AID OF CHIRAL LACTAM-PHOSPHINE LIGAND

Tomioka Kiyoshi; Nakagawa Yuichi

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >ENANTIOSELECTIVE CONJUGATE ADDITION OF ORGANOMETALLIC REAGENTS TOCYCLOALKENONES BY THE AID OF CHIRAL LACTAM-PHOSPHINE LIGAND

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ENANTIOSELECTIVE CONJUGATE ADDITION OF ORGANOMETALLIC REAGENTS TOCYCLOALKENONES BY THE AID OF CHIRAL LACTAM-PHOSPHINE LIGAND

机译：手性内酰胺-磷配体的辅助对映体共轭环烯酮的对映选择性偶联

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The chiral lactam-phosphine ligand and copper salt mediated asymmetric conjugate addition reaction of butylmagnesium chloride and diethylzinc with cycloalkenones.Among phosphines examined,5-((diphenyl-phosphino)methyl)-3,3-dimethylpyrrolidin-2-one (1) gave rise to good selectivity and high yield.

机译：手性内酰胺-膦配体和铜盐介导的丁基氯化镁和二乙基锌与环烯酮的不对称共轭加成反应。在膦中，研究了5-（（（二苯基-膦基）甲基）-3,3-二甲基吡咯烷酮-2-酮（1）产生了良好的选择性和高收率。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2000年第1期| 共3页
作者
Tomioka Kiyoshi; Nakagawa Yuichi;
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1. ENANTIOSELECTIVE CONJUGATE ADDITION OF ORGANOMETALLIC REAGENTS TOCYCLOALKENONES BY THE AID OF CHIRAL LACTAM-PHOSPHINE LIGAND [J] . Tomioka Kiyoshi, Nakagawa Yuichi Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2000 ,第1期

机译：手性内酰胺-磷配体的辅助对映体共轭环烯酮的对映选择性偶联
2. Catalytic Enantioselective Conjugate Addition of Grignard Reagents to Cyclic Enones Using C ₁-1,1a?2-Bisisoquinoline-Based Chiral Ligands [J] . Gao Qi, Zaher M. A. Judeh Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 2012 ,第11期

机译：C _{1 -1,1a？2-双异喹啉基手性配体催化格氏试剂与环烯酮的催化对映选择性偶联}
3. Catalytic enantioselective conjugate addition of Grignard reagents to cyclic enones using C _1-1,1′-bisisoquinoline-based chiral ligands [J] . Qi G., Judeh Z.M.A. Synthetic Communications . 2012 ,第10a12期

机译：使用基于C _1-1,1'-双异喹啉的手性配体将格氏试剂催化对映体选择性加成到环烯酮上
4. Tropos Benzophenone-like Phosphoramidite Ligands: Highly Enantioselective Catalyses of Conjugate Addition to Nitroalkenes irrespective of the Reagents and Substrates [C] . Kazuki Wakabayashi, Kohsuke Aikawa, Koichi Mikami Symposium on Organometallic Chemistry . 2007

机译：Tropos二苯酮样磷酰亚胺配体：无论试剂和衬底如何，硝基烯烃的缀合物的高度映射性催化剂
5. Copper-catalyzed enantioselective conjugate additions of organometal reagents to unsaturated carbonyls: An enantioselective total synthesis of clavirolide C [D] . Brown, Michael Kevin 2008

机译：铜催化的有机金属试剂对不饱和羰基化合物的对映选择性共轭加成：克拉维洛利C的对映选择性全合成
6. Copper-catalyzed enantioselective conjugate addition of organometallic reagents to challenging Michael acceptors [O] . Delphine Pichon, Jennifer Morvan, Christophe Crévisy, 2020

机译：铜催化的对映选择性缀合物加入有机金属试剂以攻击迈克尔受体
7. Catalytic enantioselective conjugate addition of organometallic reagents [O] . de Vries Andreas Hendrikus Maria 1996

机译：有机金属试剂的催化对映选择性共轭加成
8. Chiral Synthesis via Organoboranes. 18. Selective Reductions. 43. Diisopinocampheylchloroborane as an Excellent Chiral Reducing Reagent for the Synthesis of Halo Alcohols of High Enantiomeric Purity. A Highly Enantioselective Synt [R] . Srebnik, M., Ramachandran, P. V., Brown, H. C. 1988

机译：有机硼烷的手性合成。 18.选择性削减。 43. Diisopinocampheylchloroborane作为一种优良的手性还原剂，用于合成高对映体纯度的卤代醇。高度对映选择性合成

ENANTIOSELECTIVE CONJUGATE ADDITION OF ORGANOMETALLIC REAGENTS TOCYCLOALKENONES BY THE AID OF CHIRAL LACTAM-PHOSPHINE LIGAND

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