DIRECT ARYLATION OF 2-PYRIDONES:PHOTOSTIMULATED SRN1 REACTION BETWEEN CESIUM PHENOXIDES AND CHLORO-2-PYRIDONES

Higuchi Hiroyuki; Hattori Masayo

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DIRECT ARYLATION OF 2-PYRIDONES:PHOTOSTIMULATED SRN1 REACTION BETWEEN CESIUM PHENOXIDES AND CHLORO-2-PYRIDONES

机译：2-吡咯烷直接芳基化：苯甲酸铯与氯-2-吡咯烷酮的光引发SRN1反应

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4-Hydroxyphenyl-(3 and 4) and 6-hydroxyphenyl-1-methyl-2-pyridones (6 and 7) were obtained by the photostimulated reaction of 4-chloro-(1) and 6-chloro-1-methyl-2-pyridone (5),respectively,with variously substituted cesium phenoxides (2).The reactions were proposed to proceed via an SRN1 mechanism.

机译：通过4-氯-（1）和6-氯-1-甲基-2的光刺激反应获得4-羟基苯基-（3和4）和6-羟基苯基-1-甲基-2-吡啶酮（6和7）。 -吡啶酮（5）分别与各种取代的苯甲酸铯（2）。建议通过SRN1机制进行反应。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2000年第1期|共8页
作者
Higuchi Hiroyuki; Hattori Masayo;
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中图分类杂环化合物;
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1. DIRECT ARYLATION OF 2-PYRIDONES:PHOTOSTIMULATED SRN1 REACTION BETWEEN CESIUM PHENOXIDES AND CHLORO-2-PYRIDONES [J] . Higuchi Hiroyuki, Hattori Masayo Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2000,第1期

机译：2-吡咯烷直接芳基化：苯甲酸铯与氯-2-吡咯烷酮的光引发SRN1反应
2. Photochemical and photophysical behavior of indolyl anions in photostimulated intramolecular arylation reactions [J] . Victoria A. Vaillard, Roberto A. Rossi, Juan E. Argiiello Organic & biomolecular chemistry . 2012,第46期

机译：吲哚阴离子在光刺激的分子内芳基化反应中的光化学和光物理行为
3. Synthesis of 6-substituted 2-pyrrolyl and indolyl benzoxazoles by intramolecular O-arylation in photostimulated reactions [J] . Vaillard V.A., Guastavino J.F., Budén M.E., The Journal of Organic Chemistry . 2012,第3期

机译：分子内O-芳基化在光刺激反应中合成6-取代的2-吡咯基和吲哚基苯并恶唑
4. Highly C3-Selective Direct Alkylation and Arylation of 2-Pyridones under Visible-Light-Promoted Photoredox Catalysis [C] . Atifah Najib, Sho Tabuchi, Koji Hirano 石油・石油化学討論会 . 2016

机译：高度C3选择性直接烷基化和2-吡啶的芳啶在可见光促进的光毒剂催化下
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Sustainable Access to π-Conjugated Molecular Materials via Direct (Hetero)Arylation Reactions in Water and under Air [O] . Adiel Mauro Calascibetta, Sara Mattiello, Alessandro Sanzone, 2020

机译：通过在水中的直接（异质）芳基化反应和空气下的可持续进入π缀合的分子材料
7. Synthesis of ε-oxo acids by photostimulated reactions of 2-(2-iodophenyl)acetate ion with carbanions by the SRN1 mechanism. Synthesis of novel 3-benzazepin-2-ones [O] . Javier F. Guastavino, María E. Budén, Carolina S. García, 2011

机译：通过sRN1机理，通过2-（2-碘苯基）乙酸根离子与碳负离子的光催化反应合成ε-含氧酸。新型3-苯并氮杂-2-酮的合成

DIRECT ARYLATION OF 2-PYRIDONES:PHOTOSTIMULATED SRN1 REACTION BETWEEN CESIUM PHENOXIDES AND CHLORO-2-PYRIDONES

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