Palladium-catalyzed asymmetric allylic alkylation using chiral prolinol-derived aminophosphine ligands

Takashi Mino; Youichi Tanaka; Koji Akita; Masami Sakamoto; Tsutomu Fujita

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Palladium-catalyzed asymmetric allylic alkylation using chiral prolinol-derived aminophosphine ligands

机译：使用手性脯氨醇衍生的氨基膦配体催化钯催化的不对称烯丙基烷基化

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摘要

Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (4) with a dimethyl malonate-BSA-LiOAc system has been successfully carried out in the presence of a new chiral prolino-derived aminophosphine ligand (3e) in good yield with good enantioselectivity (up to 96% ee).

机译：在新的手性脯氨酸衍生的氨基膦配体（3e）的存在下，已成功地进行了丙二酸丙二酯-BSA-LiOAc体系钯催化的1,3-二苯基-2-丙烯基乙酸丙烯酯（4）的钯不对称烯丙基烷基化反应。良好的收率和良好的对映选择性（高达96％ee）。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2003年第1期|共5页
作者
Takashi Mino; Youichi Tanaka; Koji Akita; Masami Sakamoto; Tsutomu Fujita;
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1. Palladium-catalyzed asymmetric allylic alkylation using chiral prolinol-derived aminophosphine ligands [J] . Takashi Mino, Youichi Tanaka, Koji Akita, Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2003,第1期

机译：使用手性脯氨醇衍生的氨基膦配体催化钯催化的不对称烯丙基烷基化
2. Palladium-catalyzed asymmetric allylic alkylation using chiral aminophosphine ligands [J] . Mino T., Akita K., Anada K., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2001,第12期

机译：使用手性氨基膦配体的钯催化不对称烯丙基烷基化
3. N,N-Disubstituted Allylic Amine Type Aminophosphines with C(aryl)-N(amine) Bond Axial Chirality: Synthesis and Application to Palladium-Catalyzed Asymmetric Allylic Alkylation with Malonates [J] . Takashi Mino, Junpei Youda, Toshibumi Ebisawa, Journal of Oleo Science . 2018,第10期

机译：具有C（芳基）-N（胺）键轴向手性的N，N-二取代的烯丙胺型氨基膦酸酯：丙二酸酯的钯催化不对称烯丙基烷基化反应的合成及应用
4. Iridium Complex-Catalyzed Asymmetric Allylic Alkylation Using Chiral Phosphoramidite Ligands with Oxazolidinone Framework [C] . Gen Onodera, Keijiro Watabe, Yasushi Kawaguchi Symposium on Organometallic Chemistry . 2006

机译：使用具有恶唑烷酮骨架的手性磷酰胺配体的铱络合物催化的不对称烯丙基化烷基化
5. Application of chiral bis(phosphine) monosulfide ligands to palladium-catalyzed asymmetric allylic alkylation. [D] . Wilt, Jeremy Clinton. 2005

机译：手性双（膦）单硫化物配体在钯催化的不对称烯丙基烷基化反应中的应用。
6. New Nitrogen Sulfur- and Selenium-Donating Ligands Derived from Chiral Pyridine Amino Alcohols. Synthesis and Catalytic Activity in Asymmetric Allylic Alkylation [O] . Marzena Wosińska-Hrydczuk, Jacek Skarżewski 2021

机译：新的氮硫 - 和硒芳烃衍生自手性吡啶氨基醇的配体。不对称烯丙基烷基化的合成与催化活性
7. Development of Chiral (S)-Prolinol-Derived Ligands for Palladium-Catalyzed Asymmetric Allylic Alkylation: Effect of a Siloxymethyl Group on the Pyrrolidine Backbone [O] . -1

机译：用于钯催化的不对称烯丙基化烷基化的手性 - 脯醇衍生配体的开发：硅氧烷甲基对吡咯烷骨架上的作用

Palladium-catalyzed asymmetric allylic alkylation using chiral prolinol-derived aminophosphine ligands

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