SYNTHESIS,STRUCTURE,AND FLUORESCENT PROPERTIES OF [2.1.2.1]METACYCLOPHANE CONTAINING 2-(9-ANTHRYL)IMIDAZOLES

Yousuke Nishiyama; Tsuyoshi Sawada; Akiko Furuta

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SYNTHESIS,STRUCTURE,AND FLUORESCENT PROPERTIES OF [2.1.2.1]METACYCLOPHANE CONTAINING 2-(9-ANTHRYL)IMIDAZOLES

机译：[2.1.2.1]含2-（9-蒽基）咪唑的甲硫酚的合成，结构和荧光性质

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The Albright-Goldman oxidation of [2.1.2.1]metacyclophane([2.1.2.1]MCP,2)containing hydroxy groups at the bridge yielded [2.1.2.1]MCP tetraone 3.The subsequent condensation reaction of 9-anthraldehyde afforded 2-(9-anthryl)imidazole-annulated [2.1.2.1]MCP 3.The UV and fluorescence spectra and their influence of sodium and lithium ion of the [2.1.2.1]MCP 2-(9-anthryl)imidazole adduct 4 were reported.

机译：在桥处含有羟基的[2.1.2.1]间环甲基（[2.1.2.1] MCP，2）的Albright-Goldman氧化得到[2.1.2.1] MCP四酮3。随后9-乙醛的缩合反应得到2-（ [2.1.2.1] MCP 3- [9-蒽基]咪唑环化剂3.报道了[2.1.2.1] MCP 2-（9--基）咪唑加合物4的紫外和荧光光谱以及钠和锂离子的影响。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2007年第10期| 共12页
作者
Yousuke Nishiyama; Tsuyoshi Sawada; Akiko Furuta;
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SYNTHESIS,STRUCTURE,AND FLUORESCENT PROPERTIES OF [2.1.2.1]METACYCLOPHANE CONTAINING 2-(9-ANTHRYL)IMIDAZOLES

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