PALLADIUM-CATALYZED DOMINO-WACKER-CARBONYLATION REACTION FOR THE ENANTIQSELECTIVE SYNTHESIS OF CHROMANS AND BENZODIOXINS

Lutz F.Tietze; Julia Zinngrebe; Dirk A.Spiegl

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PALLADIUM-CATALYZED DOMINO-WACKER-CARBONYLATION REACTION FOR THE ENANTIQSELECTIVE SYNTHESIS OF CHROMANS AND BENZODIOXINS

机译：钯催化的多米诺-瓦克碳酰化反应用于铬和苯并二恶英的选择性合成

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A palladium-catalyzed domino reaction for the formation of chromans 9 as well as 10 and benzodioxins 13 is described starting from the alkenes 6 as well as 8 and the allyl phenyl ethers 12.The domino reaction comprises an enantioselective intramolecular Wacker oxidation,a subsequent CO-insertion and a nucleophilic substitution of the intermediately formed palladium-species.

机译：从烯烃6以及8和烯丙基苯基醚12开始，描述了钯催化的用于生成苯并二恶英9、10和苯并二恶英13的多米诺反应。多米诺反应包括对映选择性分子内Wacker氧化，随后的CO -插入和中间形成的钯物种的亲核取代。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2007年第0期| 共17页
作者
Lutz F.Tietze; Julia Zinngrebe; Dirk A.Spiegl;
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1. PALLADIUM-CATALYZED DOMINO-WACKER-CARBONYLATION REACTION FOR THE ENANTIQSELECTIVE SYNTHESIS OF CHROMANS AND BENZODIOXINS [J] . Lutz F.Tietze, Julia Zinngrebe, Dirk A.Spiegl Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007 ,第0期

机译：钯催化的多米诺-瓦克碳酰化反应用于铬和苯并二恶英的选择性合成
2. A highly efficient enantioselective synthesis of 2-methyl chromans via four sequential palladium-catalyzed reactions [J] . Michael Palucki, Nobuyoshi Yasuda Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005 ,第6期

机译：通过四个连续的钯催化反应高效合成2-甲基苯并二氢吡喃
3. A highly efficient enantioselective synthesis of 2-methyl chromans via four sequential palladium-catalyzed reactions [J] . Michael Palucki, Nobuyoshi Yasuda Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005 ,第6期

机译：通过四个连续的钯催化反应高效合成2-甲基苯并二氢吡喃
4. Utilization of palladium-catalyzed C-C and C-N bond formation reactions in the synthesis of six-membered oxygen heterocycles [C] . Tamas Patonay, Anita Abraham, Szabolcs Fekete European Symposium on Organic Chemistry . 2009

机译：利用钯催化的C-C和C-N键形成反应在六元氧杂环的合成中
5. 1. Axially-chiral 7-membered N-heterocyclic carbenes: Synthesis and application to palladium-catalyzed intramolecular aerobic oxidation of olefins 2. Development of palladium-catalyzed aerobic oxidative olefin amination reactions [D] . Scarborough, Christopher C. 2008

机译：1.轴向手性7元N-杂环卡宾：烯烃的钯催化分子内需氧氧化的合成及应用2.钯催化需氧氧化烯烃胺化反应的发展
6. Doubly Decarboxylative Synthesis of 4-(Pyridylmethyl)chroman-2-ones and 2-(Pyridylmethyl)chroman-4-ones under Mild Reaction Conditions [O] . Jan Bojanowski, Anna Albrecht 2021

机译：在轻度反应条件下双脱羧合成4-（吡啶甲基）铬-2-铬-2-铬和2-（吡啶基甲基）Chroman-4-苯并
7. A One-Pot Regiospecific Synthesis of Highly Functionalized 1,4-Benzodioxin Derivatives from an Electrochemically Induced Diels—Alder Reaction. [O] . Daiwang Xu, Angele Chiaroni, Martine Largeron 2006

机译：从电化学诱导的Diels-Alder反应中的一种高官能化1,4-苯并喹蛋白衍生物的单盆性细胞细胞再性合成。

PALLADIUM-CATALYZED DOMINO-WACKER-CARBONYLATION REACTION FOR THE ENANTIQSELECTIVE SYNTHESIS OF CHROMANS AND BENZODIOXINS

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