Effective synthesis of a carbon-linked diazirinyl fatty acid derivative via reduction of the carbonyl group to methylene with triethylsilane and trifluoroacetic acid

Makoto Hashimoto; Yasumaru Hatanaka; Kensuke Nabeta

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >Effective synthesis of a carbon-linked diazirinyl fatty acid derivative via reduction of the carbonyl group to methylene with triethylsilane and trifluoroacetic acid

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Effective synthesis of a carbon-linked diazirinyl fatty acid derivative via reduction of the carbonyl group to methylene with triethylsilane and trifluoroacetic acid

机译：通过用三乙基硅烷和三氟乙酸将羰基还原为亚甲基，有效合成碳连接的二叠氮基脂肪酸衍生物

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Friedel-Crafts acylation of the aryldiazirine with omega-ester-alpha-acyl halide and successive reduction of the carbonyl group to methylene with triethylsilane and trifluoroacetic acid gave diazirinylated fatty acids.

机译：用ω-酯-α-酰卤对芳基二嗪进行弗里德尔-克拉夫茨酰化反应，然后用三乙基硅烷和三氟乙酸将羰基连续还原为亚甲基，得到重氮基化脂肪酸。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2003年第1期|共4页
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Makoto Hashimoto; Yasumaru Hatanaka; Kensuke Nabeta;
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1. Effective synthesis of a carbon-linked diazirinyl fatty acid derivative via reduction of the carbonyl group to methylene with triethylsilane and trifluoroacetic acid [J] . Makoto Hashimoto, Yasumaru Hatanaka, Kensuke Nabeta Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2003,第1期

机译：通过用三乙基硅烷和三氟乙酸将羰基还原为亚甲基，有效合成碳连接的二叠氮基脂肪酸衍生物
2. Trifluoroacetic acid: a more effective and efficient reagent for the synthesis of 3-arylmethylene-3,4-dihydro-1H-quinolin-2-ones and 3-arylmethyl-2-amino-quinolines from Baylis-Hillman derivatives via Claisen rearrangement [J] . Pathak R, Madapa S, Batra S Tetrahedron . 2007,第2期

机译：三氟乙酸：一种通过Bayes-Hillman衍生物通过克莱森重排合成3-芳基亚甲基-3,4-二氢-1H-喹啉-2-酮和3-芳基甲基-2-氨基-喹啉的更有效的试剂
3. The Ugi reaction with CF3-carbonyl compounds: effective synthesis of alpha-trifluoromethyl amino acid derivatives [J] . Gulevich AV, Shevchenko NE, Balenkova ES, Tetrahedron . 2008,第51期

机译：与CF3-羰基化合物的Ugi反应：有效合成α-三氟甲基氨基酸衍生物
4. Fluoroform, Fluoral, Trifluoroacetic, and Trifluoromethanesulfmic Acids Derivatives as New Reagents for the Introduction of Polyfluorinated Moieties [C] . Bernard R. Lagnlois, Thierry Billard American Chemical Society Symposium on Fluorine-Containing Synthons . 2005

机译：含氟类，氟，三氟乙酸和三氟甲磺酸衍生物作为新试剂，用于引入多氟化部分
5. Manganese carbonyl-catalyzed reduction of carbon dioxide in metallocarboxylic acids and their derivatives. [D] . Cavanaugh, Marisa DiBiase. 1998

机译：羰基锰催化的金属羧酸及其衍生物中二氧化碳的还原。
6. Synthesis of chloromethyl ketone derivatives of fatty acids. Their use as specific inhibitors of acetoacetyl-coenzyme A thiolase cholesterol biosynthesis and fatty acid synthesis. [O] . D P Bloxham, R A Chalkley, S J Coghlin, 1978

机译：脂肪酸的氯甲基酮衍生物的合成。它们用作乙酰乙酰辅酶A硫解酶胆固醇生物合成和脂肪酸合成的特异性抑制剂。
7. Effective synthesis of a carbon-linked diazirinyl fatty acid derivative via reduction of the carbonyl group to methylene with triethylsilane and trifluoroacetic acid [O] . Hashimoto Makoto, Hatanaka Yasumaru, Nabeta Kensuke 2003

机译：通过用三乙基硅烷和三氟乙酸将羰基还原为亚甲基，有效合成碳连接的二叠氮基脂肪酸衍生物
8. Synthesis and Biological Evaluation of (E)-19-Iodo-3,3-Dimethyl-18-Nonadecenoic Acid, a New Dimethyl-Branched Long-Chain Fatty Acid to Evaluate Regional Myocardial Fatty Acid Uptake [R] . Goodman, M. M., Ambrose, K. R., Neff, K. H., 1986

机译：（E）-19-碘-3,3-二甲基-18-十一碳烯酸（一种新的二甲基支链长链脂肪酸）的合成和生物学评价，用于评估局部心肌脂肪酸的摄取

Effective synthesis of a carbon-linked diazirinyl fatty acid derivative via reduction of the carbonyl group to methylene with triethylsilane and trifluoroacetic acid

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