Bis(Ethylenethio)Tetraselenafulvalene and Related Hybrid Diselenadithiafulvalenes as Novel Electron Donores Forming Highly Conductive Complexes with 7,7,8,8-Tetracyanoquinodimethane

Mie Kodani; Satoshi Murakami; Tetsuya Jiami; Kazuo Takimiya; Yoshio Aso; Tetsuo Otsubo

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Bis(Ethylenethio)Tetraselenafulvalene and Related Hybrid Diselenadithiafulvalenes as Novel Electron Donores Forming Highly Conductive Complexes with 7,7,8,8-Tetracyanoquinodimethane

机译：双（亚乙基硫基）四硒富勒烯和相关的杂二烯二硫富勒烯作为新型电子受体，与7,7,8,8-四氟甲基喹啉甲烷形成高导电络合物

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The title tetraselenafulvalene (BET-TSF) and four related hybrid diselenadithiafulvalenes (STF) have been synthesized as a five-membered heterocycle-fused tetrathiafulvalene type of novel electron donors, which from highly conducting molecular complexes with 7,7,8,8-tetracyanoquinodimethane. In particular, the complex of BET-TSF shows a room-temperature conductivity of 2600 S cm~(-1), which is of the highest class for a molecular complex.

机译：标题四硒富烯富烯（BET-TSF）和四种相关的杂二硒二富富烯烯（STF）已合成为五元杂环稠合的四硫富富烯类型的新型电子给体，其由具有7,7,8,8-四氰基喹啉的高传导分子复合物组成。特别地，BET-TSF的复合物显示出2600S cm-（-1）的室温电导率，这对于分子复合物是最高级别的。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2001年第1期|共11页
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Mie Kodani; Satoshi Murakami; Tetsuya Jiami; Kazuo Takimiya; Yoshio Aso; Tetsuo Otsubo;
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1. Bis(Ethylenethio)Tetraselenafulvalene and Related Hybrid Diselenadithiafulvalenes as Novel Electron Donores Forming Highly Conductive Complexes with 7,7,8,8-Tetracyanoquinodimethane [J] . Mie Kodani, Satoshi Murakami, Tetsuya Jiami, Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2001,第1期

机译：双（亚乙基硫基）四硒富勒烯和相关的杂二烯二硫富勒烯作为新型电子受体，与7,7,8,8-四氟甲基喹啉甲烷形成高导电络合物
2. Radiation damage analysis of 7,7,8,8,-tetracyanoquinodimethane (TCNQ) and 2,3,5,6,-tetrafluoro-7,7,8,8,-tetracyanoquinodimethane (F{sub}4TCNQ) by electron diffraction and electron energy loss spectroscopy [J] . Masanori Koshino, Yuko Hasegawa Masunaga, Takashi Nemoto, Micron: The international research and review journal for microscopy . 2005,第3期

机译：用电子衍射法分析7,7,8,8，-四氰基喹二甲烷（TCNQ）和2,3,5,6，-四氟-7,7,8,8，-四氰基喹二甲烷（F {sub} 4TCNQ）的辐射损伤电子能量损失谱
3. Electrochemical formation of porous copper 7,7,8,8-tetracyanoquinodimethane and copper 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane honeycomb surfaces with superhydrophobic properties [J] . Manika Mahajan, Suresh K. Bhargava, Anthony P. OMullane Electrochimica Acta . 2013,第Null期

机译：具有超疏水特性的多孔铜7,7,8,8-四氰基喹二甲烷和2,3,5,6-四氟-7,7,8,8-四氰基喹二甲烷蜂窝表面的电化学形成
4. Highly polarizable metallic complexes for nonlinear optics copper(II) andnickel(II) complexes of bis(salicylaldiminato) Schiff base, [C] . Abdalla M. Darwish, Alabama AM Univ., Huntsville, Nonlinear Optical Properties of Organic Materials IX . 1996

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5. (1) Reaction of iron(0) carbene complexes with hexafluorobutyne to form bis(trifluoromethylated) furans. (2) Cycloaddition reactions of vinylketene iron(0) with 1-chloroalkynes to form highly substituted chlorocatechol derivatives. [D] . Akhani, Ravish. 2009

机译：（1）铁（0）卡宾配合物与六氟丁炔反应形成双（三氟甲基化）呋喃。（2）乙烯酮铁（0）与1-氯炔烃的环加成反应，形成高度取代的氯邻苯二酚衍生物。
6. Synthesis and Electrochemical Proprieties of Novel Unsymmetrical Bis-Tetrathiafulvalenes and Electrical Conductivity of Their Charge Transfer Complexes with Tetracyanoquinodimethane (TCNQ) [O] . Tahar Abbaz, Amel Bendjeddou, Abdelkrim Gouasmia, 2012

机译：新型不对称双四硫富瓦烯的合成电化学性质及其与四氮杂喹啉甲烷（TCNQ）的电荷转移配合物的电导率
7. Tetrathiafulvalene–7,7,8,8-tetracyanoquinodimethane and tetrathiafulvalene–2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane organic charge-transfer complexes: Reusable catalysts for electron-transfer reactions [O] . Hoshyargar Faegheh, OMullane Anthony P. 2016

机译：四硫富瓦烯–7,7,8,8-四氰基喹二甲烷和四硫富富烯–2,3,5,6-四氟-7,7,8,8-四氰基喹二甲烷有机电荷转移复合物：可重复使用的电子转移反应催化剂

Bis(Ethylenethio)Tetraselenafulvalene and Related Hybrid Diselenadithiafulvalenes as Novel Electron Donores Forming Highly Conductive Complexes with 7,7,8,8-Tetracyanoquinodimethane

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