A RING-OPENING CROSS-METATHESIS REACTION OF N-TRIALKYLSILYL 2-AZABICYCLO[2.2.1]HEPT-5-EN-3-ONE WITH ALLYLTRIMETHYLSILANE

Minoru Ishikura; Miyako Hasunuma; Kazuo Yanada

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A RING-OPENING CROSS-METATHESIS REACTION OF N-TRIALKYLSILYL 2-AZABICYCLO[2.2.1]HEPT-5-EN-3-ONE WITH ALLYLTRIMETHYLSILANE

机译：N-三烷基甲硅烷基2-氮杂双环[2.2.1] HEPT-5-EN-3-ONE与烯丙基三甲基硅烷的开环交叉复分解反应

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Subjection of N-trialkylsilyl-2-azabicyclo[2.2.1]hept-5-en-3-one (1) to a ring-opening cross-metathesis reaction with allyltrimethylsilane in the presence of Grubbs' catalyst was found to allow the predominate formation of pyrrolidine (3) over pyrrolidine (4).

机译：发现在Grubbs催化剂存在下，N-三烷基甲硅烷基-2-氮杂双环[2.2.1]庚-5-烯-3-酮（1）与烯丙基三甲基硅烷发生开环交叉复分解反应在吡咯烷（4）上形成吡咯烷（3）。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2005年第11期| 共6页
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Minoru Ishikura; Miyako Hasunuma; Kazuo Yanada;
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1. A RING-OPENING CROSS-METATHESIS REACTION OF N-TRIALKYLSILYL 2-AZABICYCLO[2.2.1]HEPT-5-EN-3-ONE WITH ALLYLTRIMETHYLSILANE [J] . Minoru Ishikura, Miyako Hasunuma, Kazuo Yanada Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2005 ,第11期

机译：N-三烷基甲硅烷基2-氮杂双环[2.2.1] HEPT-5-EN-3-ONE与烯丙基三甲基硅烷的开环交叉复分解反应
2. Improvement in the regioselectivity in the ruthenium-catalyzed metathesis reaction of 2-azabicyclo[2.2.1]-hept-5-en-3-one(ABH) with allyltrimethylsilane [J] . Minoru Ishikura, Miyako Hasunuma, Makoto Saijo Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2004 ,第1期

机译：2-氮杂双环[2.2.1]-庚-5-烯-3-酮（ABH）与烯丙基三甲基硅烷在钌催化的复分解反应中区域选择性的提高
3. Investigation of the Ring-opening Cross-Metathesis Reaction of 2-Azabicyclo-[2.2.1]hept-5-en-3-one (ABH) with Allylsilanes [J] . Minoru Ishikura, Makoto Saijo, Ayako Hino Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2003 ,第2期

机译：2-氮杂双环-[2.2.1]庚-5-烯-3-酮（ABH）与烯丙基硅烷的开环交叉复分解反应的研究
4. Novel Diblock Copolymers with Cross-linkable Side Chains Derived from 5-(Merthacryloyl amino methyl)bicyclo2.2.1hept-2-ene and 5-(Phthalimide methyl)bicyclo2.2.1hept-2-ene via Ring-Opening Metathesis Polymerization [C] . . -1

机译：5-（甲基丙烯酰基氨基甲基）双环2.2.1庚-2-烯和5-（邻苯二甲酰亚胺甲基）双环2.2.1庚-2-烯衍生的具有可交联侧链的新型双嵌段共聚物开放复分解聚合
5. Synthesis and reactions of 6-azabicyclo[3.2.1]octanes and 2-azabicyclo[2.1.1]hexanes. [D] . Rapolu, Deepa. 2008

机译：6-氮杂双环[3.2.1]辛烷和2-氮杂双环[2.1.1]己烷的合成及反应。
6. Enol Ethers as Substrates for Efficient Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes. Utility in Chemical Synthesis and Mechanistic Attributes [O] . Miao Yu, Ismail Ibrahem, Masayuki Hasegawa, -1

机译：烯醚作为底物的高效Z-和对映选择性开环/交叉复分解反应的立体源钼配合促进。实用的化学合成和机械属性
7. Synthesis of Nucleosides and Related Compounds. Part XX. Synthesis of Carbocyclic Nucleosides from 2-Azabicyclo(2.2.1)hept-5-en-3-ones: Sodium Borohydride-Mediated Carbon-Nitrogen Bond Cleavage of Five-and Six-Membered Lactams. [O] . Nobuya KATAGIRI, Makoto MUTO, Masahiro NOMURA, 1991

机译：核苷和相关化合物的合成。 XX部分。 2-氮杂双环（2.2.1）Hept-5-en-3-含有碳环核苷的合成：硼氢化钠介导的五和六元内酰胺的碳 - 氮粘合裂解。

A RING-OPENING CROSS-METATHESIS REACTION OF N-TRIALKYLSILYL 2-AZABICYCLO[2.2.1]HEPT-5-EN-3-ONE WITH ALLYLTRIMETHYLSILANE

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