NOVEL METHOD FOR THE SYNTHESIS OF beta-LACTAMS BY THE REACTION OF alpha-BROMOCARBOXYLIC ACIDS WITH IMINES MEDIATED BY TRIPHENYLPHOSPHINE

Satoshi Kikuchi; Yukihiko Hashimoto

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NOVEL METHOD FOR THE SYNTHESIS OF beta-LACTAMS BY THE REACTION OF alpha-BROMOCARBOXYLIC ACIDS WITH IMINES MEDIATED BY TRIPHENYLPHOSPHINE

机译：通过α-溴代羧酸与三苯甲基膦介导的胺反应合成β-内酰胺的新方法

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The useful and simple method for the formation of the beta-lactams by the reaction between alpha-bromo carboxylic acids and imines is described.This reaction was effectively mediated by triphenylphosphine or polystyryl-diphenylphosphine to give the beta-lactams in good yields with high trans-selectivity.

机译：描述了一种通过α-溴代羧酸与亚胺之间的反应形成β-内酰胺的有用而简单的方法，该反应是由三苯膦或聚苯乙烯基-二苯膦有效地介导的，以高收率得到高收率的β-内酰胺-选择性。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2006年第3期| 共5页
作者
Satoshi Kikuchi; Yukihiko Hashimoto;
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1. NOVEL METHOD FOR THE SYNTHESIS OF beta-LACTAMS BY THE REACTION OF alpha-BROMOCARBOXYLIC ACIDS WITH IMINES MEDIATED BY TRIPHENYLPHOSPHINE [J] . Satoshi Kikuchi, Yukihiko Hashimoto Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2006 ,第3期

机译：通过α-溴代羧酸与三苯甲基膦介导的胺反应合成β-内酰胺的新方法
2. TRANS DIASTEREOSELECTIVE SYNTHESIS OF 3-ALKYL SUBSTITUTED BETA-LACTAMS VIA THE ACID CHLORIDE-IMINE REACTION OF NONACTIVATED ACID CHLORIDES [J] . Browne M., Caplen MA., Chen LY., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995 ,第15期

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3. Stereoselective synthesis of racemic alpha-amino-acid derivatives with a beta-lactam skeleton: Application of the Staudinger reaction to chiral imines of methyl glyoxylate [J] . Barreau M., Mignani S., Mouysset D., Tetrahedron . 1998 ,第38期

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4. A facile synthesis of diastereoisomeric sulfur containing stable 1,4-diionic organophosphorus compounds through the reaction of 1,3-diethyl-2- thiobarbituric acid and activated acetylenic esters in the presence of triphenylphosphine(Abstracts) [C] . Nourollah Hazeri, Malek Taher Maghsoodlou, Sayyed Mostafa Habibi Khorassani European Symposium on Organic Chemistry . 2007

机译：通过1,3-二乙基-2-硫脲脲酸和在三苯基膦（摘要）存在下，通过1,3-二乙基-2-硫脲脲酸和活化的乙炔酯的反应，含有稳定的1,4-二硫酸有机磷化合物的非对映异构体硫的合成。
5. NEW SYNTHETIC METHODS IN ORGANIC CHEMISTRY: PART I. THE SYNTHESIS AND REACTIVITY OF STERICALLY HINDERED NITRIMINES--SYNTHESIS OF IMINES. PART II. INVESTIGATIONS INTO THE SYNTHESIS AND COUPLING REACTIONS OF 1,3-DITHIOLE ANALOGS. [D] . RUSSO, JOSEPH MICHAEL. 1986

机译：有机化学的新合成方法：第一部分：空间受限的亚硝酸盐的合成和反应性—氨基酸的合成。第二部分1,3-二噻吩类似物的合成和偶联反应的研究。
6. Titanium-mediated reductive cross-coupling reactions of imines with terminal alkynes: An efficient route for the synthesis of stereodefined allylic amines [O] . Kebin Mao, Guoqin Fan, Yuanhong Liu, 2013

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7. Cycloaddition Reaction of Imines with Acid Chlorides in the Presence of a Tertiary Base: Variation of the Methods for the Synthesis of Beta Lactams [O] . Bimal Krishna Banik 2017

机译：亚胺与酰氯在第三基础存在下的环加成反应：β内酰胺合成方法的变异

NOVEL METHOD FOR THE SYNTHESIS OF beta-LACTAMS BY THE REACTION OF alpha-BROMOCARBOXYLIC ACIDS WITH IMINES MEDIATED BY TRIPHENYLPHOSPHINE

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