Total Synthesis Of (±)-Xyloketal D And Model Studies Towards The Total Synthesis Of (-)-Xyloketal A

摘要

A stereoselective total synthesis of (±)-xyloketal D (±-2) has been achieved using a cycloaddition reaction of an 0rtho-quinone methide and a dihydrofuran as a key step. Preliminary model studies towards the total synthesis of xyloketal A (1) are also reported.