A unified approach to the enantioselective synthesis of 2,6-cis and trans disubstituted tetrahydropyranones

Caroline J.Diaz; Kyle A.Emmitte; Michael T.Crimmins

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A unified approach to the enantioselective synthesis of 2,6-cis and trans disubstituted tetrahydropyranones

机译：对映选择性合成2,6-顺式和反式双取代四氢吡喃酮的统一方法

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摘要

A stereoselective construction of cis- and trans-2,6-disubstituted tetrahydropyranones,based on strategy which combines an asymmetric alkylation and ring closing metathesis for the formation of a cyclic enol ether,is reported.

机译：据报道，基于将不对称烷基化和闭环易位结合形成环烯醇醚的策略，立体选择性地构建了顺式和反式2,6-二取代的四氢吡喃酮。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2004年第1期|共5页
作者
Caroline J.Diaz; Kyle A.Emmitte; Michael T.Crimmins;
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正文语种 eng
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1. A unified approach to the enantioselective synthesis of 2,6-cis and trans disubstituted tetrahydropyranones [J] . Caroline J.Diaz, Kyle A.Emmitte, Michael T.Crimmins Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2004,第1期

机译：对映选择性合成2,6-顺式和反式双取代四氢吡喃酮的统一方法
2. The Biomimetic Synthesis and First Characterization of the (+)- and (−)-Isocentrolobines, 2,6-cis- and 2,6-trans-Disubstituted Tetrahydro-2H-pyrans [J] . Frank Rogano Georges Froidevaux Peter Rüedi Helvetica Chimica Acta . 2010,第7期

机译：（+）-和（-）-异麦角蛋白，2,6-顺式和2,6-反式-二取代四氢-2H-吡喃的仿生合成和首次表征
3. The biomimetic synthesis and first characterization of the (+)- and (-)-isocentrolobines, 2,6-cis- and 2,6-trans-disubstituted tetrahydro-2H-pyrans [J] . Rogano F., Froidevaux G., Rüedi P. Helvetica chimica acta . 2010,第7期

机译：（+）-和（-）-异麦角蛋白，2,6-顺式和2,6-反式-二取代的四氢-2H-吡喃的仿生合成和首次表征
4. Enantioselective Photodimerization of a 2,6-Disubstituted Anthracene Derivative Assisted by a One-Handed Homo-Double Helix Formation [C] . Akio Urushima, Makoto Tanaka, Naomichi Horimoto 日本化学会春季年会講演予稿集 . 2018

机译：通过单手同源双螺旋形成辅助2,6二二偶蒽衍生物的映选择性光电二聚体
5. A second-generation total synthesis of leucascandrolide A: A Mukaiyama aldol-Prins approach, and, Progress towards a reagent-controlled, stereoselective synthesis of 2,5-cis and 2,5-trans substituted tetrahydrofuran rings. [D] . Van Orden, Lori Jean. 2007

机译：白藜芦醇酯A的第二代全合成：Mukaiyama aldol-Prins方法，并且向2，5-顺式和2，5-反式取代的四氢呋喃环的试剂控制的立体选择性合成进展。
6. Stereoselective Synthesis of cis- or trans-35-Disubstituted Pyrazolidines via Pd-Catalyzed Carboamination Reactions. Use of Allylic Strain to Control Product Stereochemistry Through N-Substituent Manipulation [O] . Natalie C. Giampietro, John P. Wolfe -1

机译：通过Pd催化的碳氨化反应立体选择性地合成顺式或反式35-二取代的吡唑烷。使用烯丙基菌株通过N取代基操纵来控制产物立体化学
7. Enantiodivergent Approach to the Synthesis of Cis-2,6-Disubstituted Piperidin-4-ones [O] . Alejandro Lahosa, Miguel Yus, Francisco Foubelo 2019

机译：CIS-2,6-二取代的哌啶-4-二取代的合成的浅发方法

A unified approach to the enantioselective synthesis of 2,6-cis and trans disubstituted tetrahydropyranones

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