REACTION OF FENCHONE HYDRAZONE WITH DISELENIUM DIBROMIDE: NOVEL FORMATION OF BICYCLIC DISELENIDE

摘要

Bicyclic diselenide containing a norbornane skeleton was synthesized by the reaction of fenchone hydrazone with Se2Br2. Initially formed selenofenchone further reacted with another molar amount of Se2Br2 to afford Wagner-Meerwein rearranged diselenide. Camphor hydrazone also reacted with Se2Br2 to afford the corresponding diselenide, whereas no rearranged product was formed.