CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDD A) REACTION

Junhua Chen; Beeraiah Baire; Thomas R. Hoye

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CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDD A) REACTION

机译：己二醛-醛（HDD A）反应生成的叠氮化物，呋喃和吡咯单元与苯的环化反应

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Benzynes can be generated by the intramolecular thermal cycloisomerization of triynes-the title HDD A reaction. We report here that these can be trapped by cycloaddition reaction with trimethylsilyl azide (1,3-dipolar) or a furan or pyrrole (4+2 Diels-Alder).

机译：苯并炔可以通过三炔的分子内热环异构化反应生成-标题HDD A反应。我们在这里报告这些可以被三甲基叠氮化硅（1，3-偶极）或呋喃或吡咯（4 + 2 Diels-Alder）的环加成反应捕获。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2014年第2期|共10页
作者
Junhua Chen; Beeraiah Baire; Thomas R. Hoye;
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1. CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDD A) REACTION [J] . Junhua Chen, Beeraiah Baire, Thomas R. Hoye Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2014,第2期

机译：己二醛-醛（HDD A）反应生成的叠氮化物，呋喃和吡咯单元与苯的环化反应
2. Intra-and Intermolecular Trapping Reactions of Benzynes Generated by Hexadehydro-Diels-Alder Reaction [J] . Haye Min Ko Bulletin of the Korean Chemical Society . 2019,第12期

机译：通过六十二羟基胺 - 桤木反应产生的苯的和分子间捕获反应
3. Dichlorination of (Hexadehydro-Diels-Alder Generated) Benzynes and a Protocol for Interrogating the Kinetic Order of Bimolecular Aryne Trapping Reactions [J] . Dawen Niu, Tao Wang, Brian P. Woods, Organic letters . 2014,第1期

机译：（六水合氢-狄尔斯-der木生成的）苯并二氯的二氯代反应和一种用于研究双分子芳烃捕获反应动力学顺序的方案
4. 1,3-Dipolar Cycloaddition Reactions of Glycosyl Azides [C] . Linghua CAO International symposium for Chinese organic chemists . 2000

机译：1,3-偶极环加成反应糖基叠氮化物
5. Enediyne to Polyyne: Spontaneity in the Biosynthesis of Uncialamycin and Intermolecular Trapping of Benzynes Generated from the Hexadehydro-Diels-Alder Reaction [D] . Chen, Junhua. 2016

机译：Enediyne到Polyyne：自发性在甲羟霉素的生物合成中的自发性，并从六十二烷基 - 桤木反应中产生的分子间诱捕苯苏斯
6. CYCLOADDITION REACTIONS OF AZIDE FURAN AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS–ALDER (HDDA) REACTION [O] . Junhua Chen, Beeraiah Baire, Thomas R. Hoye -1

机译：己二醛-醛（HDDA）反应生成的叠氮化物呋喃和吡咯单元与苯的环化反应
7. Cycloaddition Reactions of Azide, Furan, and Pyrrole Units with Benzynes Generated by the Hexadehydro-Diels–Alder (HDDA) Reaction [O] . Thomas R. Hoye, Junhua Chen, Beeraiah Baire 2014

机译：叠氮化物，呋喃和吡咯单元与六十二醇二脉 - 桤木（HDDA）反应产生的苯乙烯的环加成反应

CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDD A) REACTION

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