ELECTROCATALYTIC OXIDATION OF BENZYL ALCOHOL AND 1-PHENETHYL ALCOHOL BY A DECAHYDROQUINOLINYL-N-OXYL-RADICAL

Kurashima Futoshi; Kashiwagi Yoshitomo

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ELECTROCATALYTIC OXIDATION OF BENZYL ALCOHOL AND 1-PHENETHYL ALCOHOL BY A DECAHYDROQUINOLINYL-N-OXYL-RADICAL

机译：癸基邻苯二甲酰基-N-氧代自由基-自由基对苯甲醇和1-苯乙醇的电催化氧化

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摘要

(+-)-trans,cis-4-Benzoyloxy-2,2,8a-trimethyldecahydroquinolinyl-n-oxyl reveals a reversible redox peak whose oxidation potential is at +0.55 V vs.Ag/AgCl.The compound catalyzed the oxidation reactions of benzyl alcohol and 1-phenethyl alcohol to benzaldehyde and acetophenone,respectively,in satisfied current efficiency (74.4-80.6%) and selectivity (100%).

机译：（+-）-反式，顺式-4-苯甲酰氧基-2,2,8a-三甲基十氢喹啉基-正氧基揭示了一个可逆的氧化还原峰，相对于Ag / AgCl，其氧化电势为+0.55 V.苯甲醇和1-苯乙醇分别制得苯甲醛和苯乙酮，电流效率（74.4-80.6％）和选择性（100％）令人满意。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |1999年第1期| 共4页
作者
Kurashima Futoshi; Kashiwagi Yoshitomo;
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1. ELECTROCATALYTIC OXIDATION OF BENZYL ALCOHOL AND 1-PHENETHYL ALCOHOL BY A DECAHYDROQUINOLINYL-N-OXYL-RADICAL [J] . Kurashima Futoshi, Kashiwagi Yoshitomo Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 1999 ,第1期

机译：癸基邻苯二甲酰基-N-氧代自由基-自由基对苯甲醇和1-苯乙醇的电催化氧化
2. Synthesis of polymeric ionic liquid microsphere/Pt nanoparticle hybrids for electrocatalytic oxidation of methanol and catalytic oxidation of benzyl alcohol [J] . Yang J., Qiu L., Liu B., Journal of Polymer Science, Part A. Polymer Chemistry . 2011 ,第21期

机译：用于甲醇电催化氧化和苯甲醇催化氧化的聚合物离子液体微球/铂纳米粒子杂化物的合成
3. Multi-vacancy Co3O4 on nickel foam synthesized via a one-step hydrothermal method for high-efficiency electrocatalytic benzyl alcohol oxidation [J] . Cao Yanming, Zhang Dongbin, Kong Xianggui, Journal of Materials Science . 2021 ,第11期

机译：通过一步水热法合成的高效电催化苄醇氧化多空液泡沫的多空位CO3O4
4. Liquid-phase catalytic oxidation of benzyl alcohol to benzyl aldehyde With Fe/La-HMS [C] . Guangwei Qiao, Lihua Jia, Xueju Zhang, 2011 International Conference on Remote Sensing, Environment and Transportation Engineering . 2011

机译：Fe / La-HMS液相催化氧化苯甲醇制苄醛
5. Electrocatalytic oxidation of alcohols using platinum and palladium nanoporous solids. [D] . Dimos, Margaretta Mary. 2011

机译：使用铂和钯纳米多孔固体对醇进行电催化氧化。
6. Ordered Mesoporous Carbon Embedded with Cu NanoparticleMaterials for Electrocatalytic Synthesis of Benzyl Methyl Carbonatefrom Benzyl Alcohol and Carbon Dioxide [O] . Qiao-Li Hu, Zhi-Xia Zhang, Jing-Jie Zhang, 2020

机译：嵌入铜纳米粒子的有序介孔碳电催化合成碳酸甲基苄酯的材料来自苄醇和二氧化碳
7. Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide [O] . -1

机译：用Cu纳米粒子材料嵌入有序介孔碳，用于电催化合成苄醇和二氧化碳的苄基碳酸甲酯
8. Determination of the Minimum Energy Conformations of Benzyl Alcohol and 2-Phenethyl Alcohol. [R] . Im, H. S., Bernstein, E. R. 1989

机译：苄醇和2-苯乙醇的最小能量构象的测定。

ELECTROCATALYTIC OXIDATION OF BENZYL ALCOHOL AND 1-PHENETHYL ALCOHOL BY A DECAHYDROQUINOLINYL-N-OXYL-RADICAL

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