Application of Thermal Analysis Methods to Studying the Kinetics of Thermal Decomposition of Energetic Materials

摘要

Studies of the formal kinetics of thermal decomposition of energetic materials in the condensed phase are necessary for estimating the reaction rates under the conditions of their synthesis,storage,processing,and use and also for solving a number of basic problems of chemical physics.Although experimental equipment is continuously being improved,the published data on the kinetic parameters of thermal decomposition of energetic materials show very wide scatters.In our opinion,these scatters are largely determined by subjective factors,first of all,insufficiently detailed design of experiments.