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Combustion and Pollutant Emission Characteristics of Lignite Dried by Low Temperature Air

机译:低温空气干燥褐煤的燃烧及污染物排放特性

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摘要

Lignite is a kind of coal that has high moisture content and needs to be dried before being utilized. In this article, a Chinese lignite was dried in air at 120-180 degrees C and the changes in its physical and chemical structures after drying were investigated. The results showed that the pore volume and specific surface area of the lignite decreased after drying. Some of the methylene and methyl groups were oxidized by the oxygen in the drying air, resulting in an increase in oxygen functional groups. The combustion characteristics of the dried coals and parent coal (dry basis) were studied via thermogravimetric analysis. The total volatile yields of the dried coals increased compared to the parent coal. The burnout temperatures of the dried coals were higher than the parent coal, whereas the ignition temperatures stayed almost unchanged. An entrained flow system was set up to study the release of nitrogenous gas products during rapid pyrolysis and combustion. The HCN yields of the dried coals during pyrolysis were higher than that of the parent coal, and a similar trend was found for the NO yield during combustion. The mechanism changes of combustion and pollutant emission characteristics were discussed according to the results of the physical and chemical structure analyses.
机译:褐煤是一种具有高水分含量的煤,需要在使用前进行干燥。在本文中,将褐煤在空气中于120-180摄氏度下干燥,并研究了干燥后其物理和化学结构的变化。结果表明,干燥后褐煤的孔体积和比表面积减小。干燥空气中的氧气将部分亚甲基和甲基氧化,导致氧官能团增加。通过热重分析研究了干煤和母煤(干基)的燃烧特性。与原煤相比,干煤的总挥发物产量增加了。干煤的燃尽温度高于母煤,而着火温度几乎保持不变。建立了气流床系统以研究快速热解和燃烧过程中含氮气体产物的释放。干煤在热解过程中的HCN产率高于母煤,在燃烧过程中发现NO的趋势相似。根据理化分析结果,探讨了燃烧机理和污染物排放特征。

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