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Corrosion performance of damaged thermally sprayed aluminium in simulated deep sea environment

机译:模拟深海环境中受损的热喷涂铝的腐蚀性能

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摘要

Thermally sprayed aluminium (TSA) has been used in offshore applications for decades. Their effectiveness in mitigating corrosion of steel structures in presence of seawater has been proven over the years. However, very little work is reported on the performance of TSA when damaged. Furthermore, data on the performance of damaged TSA in deep sea is virtually non-existent. The paper addresses this knowledge gap and reports the corrosion performance of damaged TSA in a simulated deep sea environment. Holiday amounting to ~3% of the sample area was drilled to expose the underlying carbon steel and the sample was exposed to synthetic seawater at 5℃ for 30 days in an autoclave at 50MPa to simulate 5000m of water pressure. After testing, examination of the sample revealed the formation of calcareous deposit on the exposed steel surface with no visible steel corrosion product. Detailed microstructural characterisation of the calcareous deposit confirmed the formation of protective Mg-based layer with negligeable Ca-based material. Thus, one can conclude that TSA can protect carbon steel in deep sea environment even when damaged.
机译:热喷涂铝(TSA)在海上应用中已经使用了数十年。多年来已经证明了它们在减轻海水中钢结构腐蚀方面的有效性。但是,关于损坏时TSA性能的报道很少。此外,关于深海中受损TSA的性能的数据几乎不存在。本文解决了这一知识差距,并报告了在模拟的深海环境中受损的TSA的腐蚀性能。钻了约3%样品区域的节假日以暴露出下面的碳钢,并在50MPa的高压釜中将样品在5℃的合成海水中暴露30天,以模拟5000m的水压。测试后,对样品的检查表明,在裸露的钢表面上形成了钙质沉积物,没有可见的钢腐蚀产物。钙质矿床的详细微观结构特征证实了钙基可忽略不计的保护性镁基层的形成。因此,可以得出结论,即使受到破坏,TSA仍可以在深海环境中保护碳钢。

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