Synthesis, crystal structure, magnetic and luminescence properties of KEuGe2O6: a europium cyclogermanate containing infinite chains of edge-sharing Eu-O polyhedra

摘要

A new Eu(III) germanate, KEuGe2O6, has been synthesized by both the flux-growth method and the high-temperature, high-pressure hydrothermal method and characterized by single-crystal X-ray diffraction. The compound contains parallel zigzag chains of edge-sharing Eu-O polyhedra, which are in turn linked by sharing vertices and edges with three-membered single ring Ge3O96- germanate anions to form a 3-D framework structure. The magnetic and luminescence properties were also investigated. The observed chi(M) T value at 300 K is 4.53 emu K mol(-1), which is in good agreement with the calculated value for three EU3+ ions. The sharp peaks in the room-temperature emission spectrum are assigned. The number of lines in the region of the D-5(0)-> F-7(0) transition and the relative intensities of the D-5(0)-> F-7(1) and D-5(0)-> F-7(2) transitions confirm the presence of two local Eu3+ environments and strongly distorted Eu3+-ligand surroundings. The reasons for the very short emission life time is discussed. The Sm and Tb analogues have also been synthesized.