Syntheses, structure, and properties of a manganese-calcium cluster containing a Mn4Ca2 core

Jerzykiewicz LB; Utko J; Duczmal M; Sobota P

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Syntheses, structure, and properties of a manganese-calcium cluster containing a Mn4Ca2 core

机译：含Mn4Ca2核的锰钙簇的合成，结构和性质

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We describe here a novel, simple, efficient self-assembly method for the in situ generation of [Mn4Cl4(mu-OCH2CH2OMe)(4)(EtOH)(4)] (1) and [Mn-4(p-Cl)Cl-3(p-OCH2CH2OMe)(4)(HOCH2CH2OMe)(3)](2) (2) cubane-type compounds which react readily with calcium species to form cluster [Mn4Ca2Cl4(mu-OCH2CH2OMe)(8)] (3), the calcium atoms attached to the Mn-4 unit of 3 flatten out the cubane inducing significant conformational changes.

机译：我们在这里描述了一种新颖，简单，有效的自组装方法，用于原位生成[Mn4Cl4（mu-OCH2CH2OMe）（4）（EtOH）（4）]（1）和[Mn-4（p-Cl）Cl -3（p-OCH2CH2OMe）（4）（HOCH2CH2OMe）（3）（2）（2）古巴型化合物，它们容易与钙离子反应形成簇[Mn4Ca2Cl4（mu-OCH2CH2OMe）（8）]（3），附着在3的Mn-4单元上的钙原子使扁豆变平，从而导致显着的构象变化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第8期|共2页
作者
Jerzykiewicz LB; Utko J; Duczmal M; Sobota P;
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正文语种 eng
中图分类无机化学;
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PHOTOSYNTHETIC WATER OXIDATION; EVOLVING PHOTOSYSTEM-II; CRYSTAL-STRUCTURE; ANGSTROM RESOLUTION; OXIDIZING COMPLEX; ACTIVE-SITE; RELEVANCE; MODELS; CUBANE; REACTIVITY;

机译：光合水氧化;不断发展的光化学体系Ⅱ;晶体结构;固溶度;氧化复合物;活性部位;相对性;模型;丁烷;反应性;

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1. Syntheses, structure, and properties of a manganese-calcium cluster containing a Mn4Ca2 core [J] . Jerzykiewicz LB, Utko J, Duczmal M, Dalton transactions: An international journal of inorganic chemistry . 2007,第8期

机译：含Mn4Ca2核的锰钙簇的合成，结构和性质
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Syntheses, structure, and properties of a manganese-calcium cluster containing a Mn4Ca2 core

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