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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The first structural examples of tricitratotitanate [Ti(H_2cit)_3]~(2-) dianions
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The first structural examples of tricitratotitanate [Ti(H_2cit)_3]~(2-) dianions

机译:三西他钛酸酯[Ti(H_2cit)_3]〜(2-)二价阴离子的第一个结构实例

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摘要

The crystal structures of the mixed-cation compounds KMg_(1/2)[Ti(H_2cit)_3]·6H_2O (H_4cit = citric acid), which were synthesized by a modified Pechini process, feature three bidentate [(HO_2CCH_2)_2-C(CO_2-)O-] citrato groups that chelate to the titanium atom through their negatively-charged α-alkoxyl and α-carboxyl oxygen atoms; the other two β-carboxylic acid groups are free.
机译:通过改进的Pechini工艺合成的混合阳离子化合物KMg_(1/2)[Ti(H_2cit)_3]·6H_2O(H_4cit =柠檬酸)的晶体结构具有三个双齿[(HO_2CCH_2)_2-C通过其带负电的α-烷氧基和α-羧基氧原子与钛原子螯合的(CO_2-)O-]柠檬酸酯基;另外两个β-羧酸基是游离的。

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