Glycoligands and Co(II)glycocomplexes.Investigation of the variation of the sugar-scaffold on the structure and chirality measured by circular dichroism

摘要

Glycoligands using various monosaccharide platforms func-tionalised by three 2-picolyl groups and coordinated to Co(II)through the bidentate 2-picolyl ether moieties are interesting ligands as they efficiently induce chirality at the cobalt with a fine control of the structure through the central sugar scaffold.