Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site

Orain PY; Capon JF; Kervarec N; Gloaguen F; Petillon F; Pichon R; Schollhammer P; Talarmina J

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Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site

机译：1,10-菲咯啉在与[Fe-Fe]氢化酶活性位点有关的二硫代二硫酸铁衍生物中的用途

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Treatment of [Fe-2(mu-pdt)( CO) 6] (pdt = S(CH2)(3)S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe-2(mu-pdt)(CO)(4)( phen)] (1); the protonation of 1 with HBF4 center dot OEt2 in CD2Cl2 at 203 K has been monitored by H-1 NMR.

机译：在回流的甲苯中用1,10-菲咯啉（phen）处理[Fe-2（mu-pdt）（CO）6]（pdt = S（CH2）（3）S）得到不对称的络合物[Fe-2（mu -pdt）（CO）（4）（phen）]（1）;通过H-1 NMR监测了在203 K下具有CD2Cl2中HBF4中心点OEt2的1的质子化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第34期|共3页
作者
Orain PY; Capon JF; Kervarec N; Gloaguen F; Petillon F; Pichon R; Schollhammer P; Talarmina J;
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正文语种 eng
中图分类无机化学;
关键词
IRON-ONLY HYDROGENASE; MODELS; COMPLEXES; CATALYSIS; REDUCTION; CHEMISTRY; LIGANDS;

机译：纯铁加氢酶;模型;络合物;催化;还原;化学;配体;

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1. Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site [J] . Orain PY, Capon JF, Kervarec N, Dalton transactions: An international journal of inorganic chemistry . 2007,第34期

机译：1,10-菲咯啉在与[Fe-Fe]氢化酶活性位点有关的二硫代二硫酸铁衍生物中的用途
2. Chelate control of diiron(I) dithiolates relevant to the [Fe-Fe]-hydrogenase active site [J] . Justice AK, Zampella G, De Gioia L, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第5期

机译：与[Fe-Fe]-加氢酶活性位点有关的二硫氰酸二铁（I）的螯合控制
3. Nitrosyl Derivatives of Diiron(l) Dithiolates Mimic the Structure and Lewis Acidity of the [FeFe]-Hydrogenase Active Site [J] . Matthew T. Olsen, Maurizio Bruschi, Luca De Gioia, Journal of the American Chemical Society . 2008,第36期

机译：Diiron（l）dithiolates的亚硝基衍生物模拟[FeFe] -Hydrogenase活性位点的结构和Lewis酸度
4. ELECTROCHEMICAL DNA SENSORS BASED ON POLYMERIC INDICATOR: USE OF A POLY(4-VINYLPYRIDINE) DERIVATIVE BEARING Os(5,6-5,6-dimethyl-1,10-phenanthroline)_2Cl~(2+) [C] . Aihua Liu, Jun-ichi Anzai Proceedings vol.2004-08; International Symposium on Chemical Sensors VI: Chemical and Biological Sensors and Analytical Systems and Joint International Meeting of the Electrochemical Society(ECS) and Electrochemical Society of Japan; 20041003-08; Honolul . 2004

机译：基于聚合物指示剂的电化学DNA传感器：使用聚（4-乙烯基吡啶）衍生物轴承Os（5,6-5,6-二甲基-1,10-菲咯啉）_2Cl〜（2+）
5. Preparation of 1,10-phenanthroline derivatives with B-ring functionalization and their application. [D] . Kohler, Lars. 2011

机译：具有B环功能化的1,10-菲咯啉衍生物的制备及其应用。
6. Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the FeFe-Hydrogenase Active Site [O] . Matthew T. Olsen, Maurizio Bruschi, Luca De Gioia, -1

机译：Diiron（I）dithiolates的亚硝基衍生物模拟FeFe加氢酶活性位点的结构和路易斯酸度
7. New Nitrosyl Derivatives of Diiron Dithiolates Related to the Active Site of the [FeFe]-Hydrogenases [O] . Olsen, Matthew T., Justice, Aaron K., Gloaguen, Frederic, 2008

机译：与[FeFe]-加氢酶活性位点有关的二硫代二硫酸亚铁的新亚硝酰基衍生物
8. Discovery of External Modulators of the Fe-Fe Hydrogenase Enzyme in Clostridium acetobutylicum. [R] . Lee, M. S., Hurley, M. M., Servinsky, M., 2015

机译：在丙酮丁醇梭菌中发现Fe-Fe氢酶的外部调节剂。

Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site

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