New route to a face-to-face biscorrole free-base and the corresponding heterobimetallic copper(III)-silver(III)complex

摘要

A meso-aryl-substituted face-to-face biscorrole was synthesised in a two-step reaction and the corresponding homo-and heterobimetallic complexes were obtained and fully characterised.Metal complexes of face-to-face bismacrocycles containing porphyrins and/or corroles are stimulating continuous endeavor due to their potential applications such as fixation/activation of dioxyeen,dinitroaen or dihydroeen.