Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

Hayami S.; Kato K.; Komatsu Y.; Fuyuhiro A.; Ohba M.

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Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

机译：具有长烷基链的钴（ii）化合物具有独特的自旋转变和宽的热滞环

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The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) _2](BF_4)_2·EtOH·0.5H _2O(1·EtOH·0.5H_2O) and [Co(C12-terpy) _2](BF_4)_2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H_2O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.

机译：具有长烷基链的钴（ii）化合物[Co（C12-terpy）_2]（BF_4）_2·EtOH·0.5H _2O（1·EtOH·0.5H_2O）和[Co（C12-terpy）_2]（BF_4 ）_2（1）的合成和表征。化合物1·EtOH·0.5H_2O表现出“重入自旋交叉”。化合物1表现出折返自旋交叉和具有宽的热滞环的多相转变。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第10期|共3页
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Hayami S.; Kato K.; Komatsu Y.; Fuyuhiro A.; Ohba M.;
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1. Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain [J] . Hayami S., Kato K., Komatsu Y., Dalton transactions: An international journal of inorganic chemistry . 2011,第10期

机译：具有长烷基链的钴（ii）化合物具有独特的自旋转变和宽的热滞环
2. Spin transition at the mesophase transition temperature in a Cobalt(II) compound with branched alkyl chains [J] . Hayami S, Moriyama R, Shuto A, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第19期

机译：具有支链烷基链的钴（II）化合物在中间相转变温度下的自旋转变
3. Mechanism of reversible spin transition with a thermal hysteresis loop in [Fe-III(qsal)(2)][Ni(dmise)(2)] center dot 2CH(3)CN: Selenium analogue of the precursor of an Fe(III) spin-crossover molecular conducting system [J] . Takahashi K, Mori H, Kobayashi H, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2009,第9a10期

机译：[Fe-III（qsal）（2）] [Ni（dmise）（2）]中心点2CH（3）CN中具有热滞回线的可逆自旋跃迁机制：Fe（III）前体的硒类似物自旋交叉分子导电系统
4. The Nonanuclear Mo(IV) {(CN)Fe(III)(3-ethoxy-saldptn)}_8Cl_4 Complex Compound Exhibits Multiple Spin Transitions Observed by Moessbauer Spectroscopy [C] . F. RENZ, P. KEREP International Conference on the Applications of the Mossbauer Effect . 2004

机译：非核Mo（IV）{（CN）Fe（III）（3-乙氧基-ALDPTN）} _ 8 Cl_4复合物化合物表现出由Moessbauer光谱观察的多个旋转转变
5. Exchange bias in magnetically coupled cobalt(II) oxide /cobalt bilayer measured with magnetic hysteresis loop and magnetotransport. [D] . Chon, David. 2013

机译：使用磁滞回线和磁传输量测量的磁性耦合氧化钴（II）/钴双层中的交换偏压。
6. Crystal structure of a looped-chain CoII coordination polymer: catena-polybis(nitrato-κO)cobalt(II)bisμ-bis(pyridin-3-ylmethyl)sulfane-κ2N:N′ [O] . Suk-Hee Moon, Joobeom Seo, Ki-Min Park 2017

机译：环链CoII配位聚合物的晶体结构：链-聚双（nitrato-κO）钴（II）双 μ-双（吡啶-3-基甲基基）环丁砜-κ2N：N
7. Hysteretic Thermal Spin-Crossover and Symmetry Breaking in Heteroleptic Fe(II) Complexes Using Alkyl Chain Substituted 2,2’-Dipyridylamine Ligands [O] . Blaise Geoghegan, Wasinee Phonsri, Peter Horton, 2019

机译：使用烷基链取代的2,2'-双吡啶胺配体，在异质Fe（II）配合物中滞质热旋转交叉和对称性

Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

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