Step-wise synthesis of inorganic-organic hybrid based on γ-octamolybdate-based tectons

摘要

With the bottom-up design principle, we use metal-ions to bridge the predesigned tectons (1 [(H_2L~1)_2(Mo _8O_(26))]·4H_2O and 3 [(H_2L ~2)(L~2)_(0.5)(Mo_8O_(26)) _(0.5)]·H_2O) so that two higher dimensional γ-octamolybdate based inorganic-organic hybrid compounds 2 [Cu ~I_2(L~1)_3(Mo_8O _(26))_(0.5)] and 4 [Ni(L~2)_2(HL ~2)_2(Mo_8O_(26))]·4H_2O are successfully obtained.