首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Accessing the long-lived near-IR-emissive triplet excited state in naphthalenediimide with light-harvesting diimine platinum(ii) bisacetylide complex and its application for upconversion
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Accessing the long-lived near-IR-emissive triplet excited state in naphthalenediimide with light-harvesting diimine platinum(ii) bisacetylide complex and its application for upconversion

机译:聚光二亚胺铂(ii)双乙酰胺配合物进入萘二酰亚胺中长寿命的近红外发射三重态激发态及其在上转换中的应用

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摘要

Room temperature near-IR phosphorescence of naphthalenediimide (NDI) was observed with NN Pt(ii) bisacetylide complex (Pt-NDI) in which the NDI was connected to Pt(ii) center via acetylide. Pt-NDI shows intense absorption of visible light and long-lived NDI-localized excited state (~3IL) (τ_T = 22.3 μs). Pt-NDI was used as a triplet sensitizer for upconversion.
机译:用NN Pt(ii)双乙炔化物络合物(Pt-NDI)观察到萘二酰亚胺(NDI)的室温近红外磷光,其中NDI通过乙炔与Pt(ii)中心连接。 Pt-NDI显示出对可见光的强烈吸收和长寿命的NDI局部激发态(〜3IL)(τ_T= 22.3μs)。 Pt-NDI用作上转换的三重态敏化剂。

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