Tetranuclear copper(i) carboxylates: The effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescence

Hietsoi O.; Filatov A.S.; Dubceac C.; Petrukhina M.A.

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Tetranuclear copper(i) carboxylates: The effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescence

机译：四核铜（i）羧酸盐：路易斯酸的逐步增加对固态结构和光致发光的影响

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X-Ray diffraction studies of three aliphatic copper(i) carboxylates revealed a tetranuclear core structure for [Cu_4(O_2CCH _2CH_3)_4] (1), [Cu_4(O _2CCF_3)(O_2CCH_2CH_3) _3] (2), and [Cu_4(O_2CCF_2CF _3)_4] (3). The effect of a stepwise increase in electrophilicity on solid-state interactions of copper(i) tetramers as well as the implications of structural variations on photoluminescent properties of the above copper(i) propionates have been discussed.

机译：三种脂族铜（i）羧酸盐的X射线衍射研究显示[Cu_4（O_2CCH _2CH_3）_4]（1），[Cu_4（O _2CCF_3）（O_2CCH_2CH_3）_3]（2）和[Cu_4（ O_2CCF_2CF _3）_4]（3）。已经讨论了亲电性逐步增加对铜（i）四聚体的固态相互作用的影响，以及结构变化对上述丙酸铜（i）的光致发光性质的影响。

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《Dalton transactions: An international journal of inorganic chemistry 》 |2011年第34期| 共6页
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Hietsoi O.; Filatov A.S.; Dubceac C.; Petrukhina M.A.;
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1. Tetranuclear copper(i) carboxylates: The effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescence [J] . Hietsoi O., Filatov A.S., Dubceac C., Dalton transactions: An international journal of inorganic chemistry . 2011 ,第34期

机译：四核铜（i）羧酸盐：路易斯酸的逐步增加对固态结构和光致发光的影响
2. Copper(II) carboxylates with 4-aminopyridine:neutral mononuclear structures,isomerism of aceto compounds and a novel tetranuclear structure [J] . Nina Lah, Joze Koller, Primoz Segedin, New Journal of Chemistry . 2002 ,第7期

机译：具有4-氨基吡啶的羧酸铜（II）：中性单核结构，乙酰化合物的异构体和新型四核结构
3. Masking of Lewis acidity trends in the solid-state structures of trichlorido- and tribromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)gallium(III) [J] . Kazakov, Igor V., Bodensteiner, Acta crystallographica. Section C, Structural chemistry. . 2014 ,第3期

机译：三氯和三溴（2,2'：6'，2''-三吡啶-κ3N，N'，N''）镓（III）固态结构中路易斯酸度趋势的掩盖
4. Modified Metal Oxide Nanostructure Deposited Semiconductor Interfaces: Tuning the Lewis Acidity of Reversibly Interacting Sites [C] . C. Baker, W. Laminack, J. L. Gole Sensors, actuators, and microsystems general session;Meeting of The Electrochemical Society . 2014

机译：修饰的金属氧化物纳米结构沉积的半导体界面：调整可逆相互作用位点的路易斯酸度
5. New photoluminescent copper(I) complexes: Impact of bridging carboxylates on solid-state structures and photophysical properties [D] . Hietsoi, Oleksandr 2011

机译：新型光致发光铜（I）配合物：桥接羧酸盐对固态结构和光物理性质的影响
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机译：具有ONN-施主希夫碱配体的四核CuII配合物的晶体结构：六-μ2-乙酰基-双（2-{（（2266-四甲基哌啶-4-基）亚氨基甲基}酚基-κ3ONN）四铜（II）
7. Synthesis, X-ray structures, and photoluminescence of heterometal trinuclear Hg(II)-Pt(I) and tetranuclear Hg(II)-Pd(I) complexes [O] . Geng-Geng Luo, 骆耿耿, Rong-Bin Huang, 2008

机译：杂金属三核Hg（II）-Pt（I）和四核Hg（II）-Pd（I）配合物的合成，X射线结构和光致发光

Tetranuclear copper(i) carboxylates: The effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescence

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