Unprecedented coexistence of cyano-bridged (Mn4CrIII)-Cr-III and (Mn2CrIII)-Cr-III heterobimetallic complexes in one single crystal

Visinescu D; Toma LM; Lloret F; Fabelo O; Ruiz-Perez C; Julve M

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Unprecedented coexistence of cyano-bridged (Mn4CrIII)-Cr-III and (Mn2CrIII)-Cr-III heterobimetallic complexes in one single crystal

机译：氰基桥联（Mn4CrIII）-Cr-III和（Mn2CrIII）-Cr-III异双金属络合物的前所未有的共存性

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The penta-[{Mn-III(4-MeO-salen)(H2O)(mu-CN)}(4)Cr-III(CN)(2)](+) and trinuclear [{Mn-III(4-MeO-salen)(H2O)(mu-CN)}(2)CrIII-(CN)(4)](-) units coexist in 1 with weak antiferromagnetic interactions which are overcome by a dc magnetic field of 2.5 T.

机译：五[[Mn-III（4-MeO-salen）（H2O）（mu-CN）}（4）Cr-III（CN）（2）]（+）和三核[{Mn-III（4- MeO-salen）（H2O）（mu-CN）}（2）CrIII-（CN）（4）]（-）单元与弱的反铁磁相互作用共存1个，可通过2.5 T的直流磁场克服。

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《Dalton transactions: An international journal of inorganic chemistry 》 |2009年第1期| 共4页
作者
Visinescu D; Toma LM; Lloret F; Fabelo O; Ruiz-Perez C; Julve M;
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正文语种 eng
中图分类无机化学 ;
关键词
CR-MN COMPLEXES; MAGNETIC-PROPERTIES; BUILDING-BLOCK; GROUND-STATE; MOLECULE MAGNETS; SLOW RELAXATION; CHAIN MAGNETS; ZIGZAG CHAINS; M-II; SPIN;

机译：CR-MN络合物;磁性体;积木;基态;分子磁体;缓慢弛豫;链磁体;之字形链;M-II;自旋;

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1. Unprecedented coexistence of cyano-bridged (Mn4CrIII)-Cr-III and (Mn2CrIII)-Cr-III heterobimetallic complexes in one single crystal [J] . Visinescu D, Toma LM, Lloret F, Dalton transactions: An international journal of inorganic chemistry . 2009 ,第1期

机译：氰基桥联（Mn4CrIII）-Cr-III和（Mn2CrIII）-Cr-III异双金属络合物的前所未有的共存性
2. Trinuclear {M-1}CN{M-2}(2) complexes (M-1 = Cr-III, Fe-III, Co-III; M-2 = Cu-II, Ni-II, Mn-II). Are single molecule magnets predictable? [J] . Atanasov M, Busche C, Comba P, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008 ,第18期

机译：三核{M-1} CN {M-2}（2）配合物（M-1 = Cr-III，Fe-III，Co-III; M-2 = Cu-II，Ni-II，Mn-II）。单分子磁铁可预测吗？
3. A single-molecular pathway from heterometallic MM ' (M = Ba-II, Mn-II; M ' = Cr-III) oxalato complexes to intermetallic composite oxides [J] . Neo KE, Ong YY, Huynh HV, Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2007 ,第10期

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5. Directed Assembly of Single-Molecule and Single-Chain Magnets: From Mononuclear High- Spin Iron(II) Complexes to Cyano-Bridged Chain Compounds [D] . Harris, Thomas David, II 2010

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6. Temperature-Induced Single-Crystal-to-Single-CrystalTransformations with Consequential Changes in the Magnetic Propertiesof Fe(III) Complexes [O] . Amit Adhikary, *, Sohel Akhtar, 2019

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7. Mechanistic aspects of the chemistry of mononuclear Cr-III complexes with pendant-arm macrocyclic ligands and formation of discrete Cr-III/Fe-II and Cr-III/Fe-II/Co-III cyano-bridged mixed valence compounds [O] . Basallote Manuel G., Bernhardt Paul V., Calvet Teresa, 2009

机译：具有悬臂大环配体的单核Cr-III配合物的化学机理以及离散的Cr-III / Fe-II和Cr-III / Fe-II / Co-III氰基桥联混合价化合物的形成
8. Study of Coexistence of Ferromagnetism and Superconductivity in Single-Crystal ErRh sub 4 B sub 4 [R] . Sinha, S. K., Crabtree, G. W., Hinks, D. G., 1981

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Unprecedented coexistence of cyano-bridged (Mn4CrIII)-Cr-III and (Mn2CrIII)-Cr-III heterobimetallic complexes in one single crystal

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