The hydrated platinum(II) ion in aqueous solution-a combined theoretical and EXAFS spectroscopic study

Hofer TS; Randolf BR; Rode BM; Persson I

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The hydrated platinum(II) ion in aqueous solution-a combined theoretical and EXAFS spectroscopic study

机译：水溶液中的水合铂（II）离子-理论和EXAFS光谱学结合研究

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The hydrated platinum(II) ion, previously characterized as square-planar in aqueous solution, has been shown by quantum mechanical charge field molecular dynamic (QMCF MD) simulations and EXAFS experiments to be hexacoordinated with two additional ligands in elongated axial positions.

机译：量子力学电荷场分子动力学（QMCF MD）模拟和EXAFS实验表明，水合铂（II）离子以前在水溶液中呈方形分布，在细长的轴向位置上与另外两个配体六配位。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第9期|共4页
作者
Hofer TS; Randolf BR; Rode BM; Persson I;
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正文语种 eng
中图分类无机化学;
关键词
RAY-ABSORPTION SPECTROSCOPY; BODY DISTRIBUTION-FUNCTIONS; PRESSURE NMR KINETICS; WATER-EXCHANGE; MOLECULAR CALCULATIONS; CONDENSED MATTER; MECHANISM; PALLADIUM(II); DYNAMICS; TETRAAQUAPALLADIUM(II);

机译：射线吸收光谱;身体分布功能;压力NMR动力学;水交换;分子计算;凝聚态;机理;钯（II）;动力学;四水合钯（II）;

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The hydrated platinum(II) ion in aqueous solution-a combined theoretical and EXAFS spectroscopic study

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