An interwoven Fe3L3 trigonal metallamacrocycle from an in situ ligand hydrolysis reaction

Zhang QF; Jiang FL; Huang YG; Wei W; Gao Q; Yang M; Xiong KC; Hong MC

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An interwoven Fe3L3 trigonal metallamacrocycle from an in situ ligand hydrolysis reaction

机译：原位配体水解反应生成的交织Fe3L3三角金属环

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Through an in situ hydrolysis reaction of the bishydrazone ligand H(4)L1 [H(4)L1=(HOC6H4)CH=NNHCO(C5H3N)CONHN=CH(C6H4OH)], in the presence of Fe(III) ions, an interwoven trigonal metallamacrocycle [Fe3L3(H2O)(3)]center dot 9H(2)O (1) [H3L = (HOC6H4)CH=NNHCO(C5H3N)CO2H] containing unusually double-layered capsule-likewater hexamers was obtained and characterized by elemental analysis, FT-IR, TGA, ESI-MS and X-ray crystallography.

机译：通过双hydr配体H（4）L1 [H（4）L1 =（HOC6H4）CH = NNHCO（C5H3N）CONHN = CH（C6H4OH）]的原位水解反应，在Fe（III）离子存在下，获得了交织的三角金属lamcrocrocycle [Fe3L3（H2O）（3）]中心点9H（2）O（1）[H3L =（HOC6H4）CH = NNHCO（C5H3N）CO2H]包含不寻常的双层胶囊状水六聚体，并进行了表征元素分析，FT-IR，TGA，ESI-MS和X射线晶体学。

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来源
《Dalton transactions: An international journal of inorganic chemistry 》 |2009年第15期| 共4页
作者
Zhang QF; Jiang FL; Huang YG; Wei W; Gao Q; Yang M; Xiong KC; Hong MC;
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正文语种 eng
中图分类化学 ;
关键词
WATER HEXAMER; MOLECULAR ARCHITECTURE; COORDINATION POLYMERS; COMPLEXES; POLYGONS; CLUSTER; EXAMPLE; HOST; FORM;

机译：水六聚体;分子结构;配位聚合物;络合物;聚合物;团簇;实例;主机;形式;

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1. An interwoven Fe3L3 trigonal metallamacrocycle from an in situ ligand hydrolysis reaction [J] . Zhang QF, Jiang FL, Huang YG, Dalton transactions: An international journal of inorganic chemistry . 2009 ,第15期

机译：原位配体水解反应生成的交织Fe3L3三角金属环
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4. Structural characterization of vanadium terpyridine complexes for the study of in-situ ligand cyclization reaction [C] . Wan-Ting Jin, Zhao-Hui Zhou Joint Conference on Chemistry . 2019

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An interwoven Fe3L3 trigonal metallamacrocycle from an in situ ligand hydrolysis reaction

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