Synthesis and Characterization of Tetrahedral Zinc(II) Complexes with 3, 6,7-Triamino-7H-[1,2,4]triazolo[4, 3-b][1,2,4]triazole as Nitrogen-Rich Ligand

摘要

Triaminotriazolotriazole (TATOT) was used as a nitrogen-rich ligand for the formation of the energetic Zn-II complexes [ZnCl2(TATOT)(2)]center dot H2O (2), [Zn(H2O)(TATOT)(3)](NO3)(2)center dot 2H(2)O (3), and [Zn(TATOT)(4)](ClO4)(2)center dot 2H(2)O (4). The zinc species were prepared in a straightforward and inexpensive synthesis. The complexes 2-4 were structurally characterized using X-ray diffraction. Additionally, the compounds were characterized using elemental analysis and infrared (IR) spectroscopy. Finally, the sensitivities toward thermal and mechanical stimuli were determined by differential thermal analysis (DTA) and BAM (Bundesanstalt fur Materialforschung und -prufung) methods.