Synthesis and Application of Trimethylsilyl Dinitramide Me3SiN(NO2)(2) as Dinitramide Transfer Reagent; Preparation of Covalent Organotellurium(IV) Dinitramides

摘要

preparation and properties of trimethylsilyl dinitramide Me3SiN(NO2)(2) are reported. Its application as dinitramide transfer reagent furnished the first covalent organotellurium(IV) bis(dinitramides) R2Te[N(NO2)(2)](2), which were characterized by multinuclear NMR spectroscopy. Alternatively, R2Te[N(NO2)(2)](2) Were synthesized from the corresponding organotellurium(IV) halides R2TeX2 with silver dinitramide.