ON CHALCOGENOLATES .206. N-THIOACETYL DITHIOCARBAMATES AND ESTERS OF N-THIOACETYL DITHIOCARBAMIC ACID [German]

摘要

Thioacetamide reacts with carbon disulfide in the presence of KH to form via the tetrabutyl ammonium salt dark yellow N-thioacetyl dithiocarbamates M[S2C-NH-CS-CH3], where M = K, Rb, Cs. The salts as well as the methyl and ethyl ester have been characterized by means of electron absorption, infrared, nuclear magnetic resonance (H-1 and C-13), and mass spectra. Attempts to synthesize N-thioacetyl dithiocarbamic acid were not successful. [References: 6]