Interplay between metal×××π interactions and hydrogen bonds: Some unusual synergetic effects of coinage metals and substituents

摘要

The ternary systems of C_2H_4 (C_2H _2 or C_6H_6)-MCN-HF (M=Cu, Ag, Au) and the respective binary systems were investigated to study the interplay between metal×××π interactions and hydrogen bonds. The metal×××π interactions in C_2H_4-MCN become stronger with the irregular order Ag