Convenient Method for Determining the Absolute Configuration of Chiral Alcohols with Racemic ~1H NMR Anisotropy Reagent, MαNP Acid: Use of HPLC-CD Detector

Yusuke Kasai; Masataka Watanabe; Nobuyuki Harada

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Convenient Method for Determining the Absolute Configuration of Chiral Alcohols with Racemic ~1H NMR Anisotropy Reagent, MαNP Acid: Use of HPLC-CD Detector

机译：外消旋〜1H NMR各向异性试剂MαNP酸测定手性醇的绝对构型的简便方法：使用HPLC-CD检测器

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摘要

A convenient method for determining the absolute configuration of chiral secondary alcohols using the racemic NMR anisotropy reagent, (±)-2-methoxy-2-(1-naphthylP propionic acid [(±)-MαNP acid], and an HPLC-CD detector was developed. The method was successfully applied to some chiral alcohols derived from (-)-α-santonin.

机译：使用外消旋NMR各向异性试剂（±）-2-甲氧基-2-（1-萘基P丙酸[（±）-MαNP酸]和HPLC-CD检测器确定手性仲醇的绝对构型的简便方法研制成功，该方法已成功地应用于一些由（-）-α-桑托宁衍生的手性醇。

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《Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry》 |2003年第4期|共5页
作者
Yusuke Kasai; Masataka Watanabe; Nobuyuki Harada;
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正文语种 eng
中图分类分子生物学;
关键词
chiral secondary alcohols; racemic derivatizing agent; 2-methoxy-2-(1-naphthyl) propionic acid; diastereomeric esters; HPLC separation; ~1H NMR anisotropy effect; α-santonin derivatives;

机译：手性仲醇;外消旋剂;2-甲氧基-2-（1-萘基）丙酸;非对映体酯;HPLC分离;〜1H NMR各向异性;α-降钙素衍生物;

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1. Convenient Method for Determining the Absolute Configuration of Chiral Alcohols with Racemic ~1H NMR Anisotropy Reagent, MαNP Acid: Use of HPLC-CD Detector [J] . Yusuke Kasai, Masataka Watanabe, Nobuyuki Harada Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2003,第4期

机译：外消旋〜1H NMR各向异性试剂MαNP酸测定手性醇的绝对构型的简便方法：使用HPLC-CD检测器
2. Novel Chiral Molecular Tools for Preparation of Enantiopure Alcohols by Resolution and Simultaneous Determination of Their Absolute Configurations by the ~1H NMR Anisotropy Method [J] . Yusuke Kasai, Junpei Naito, Shunsuke Kuwahara, 有機合成化学協会誌 . 2004,第11期

机译：通过拆分和〜1H NMR各向异性方法同时测定其绝对构型的对映体纯醇的新型手性分子工具
3. Practical Enantioresolution of Alcohols with 2-Methoxy-2-(1-naphthyl)propionic Acid and Determination of Their Absolute Configurations by the ~1H NMR Anisotropy Method [J] . Hiromi Taji, Yusuke Kasai, Akinori Sugio, Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2002,第1期

机译：用2-甲氧基-2-（1-萘基）丙酸对醇进行实际对映拆分并通过〜1H NMR各向异性方法确定其绝对构型
4. Absolute Configuration Determination by ECD, 1HNMR,and X-Ray Methods: Principles Applications [C] . Nobuyuki Harada The 5th symposium on molecular chirality of Chinese Chemical Society amp; International Chiral Meeting . 2012

机译：通过ECD，1HNMR和X射线方法确定绝对构型：原理与应用
5. Determination of the Absolute Configuration of β-Chiral Primary Alcohols Using the Competing Enantioselective Conversion Method Heteroatom-directed Acylation of Secondary Alcohols to Assign Absolute Configuration Total Synthesis of Illisimonin a Osmate Es [D] . Burns, Alexander Sunshine. 2020

机译：使用竞争对映选择性转化法测定β-chiral初级醇的绝对构型次原子为仲醇的酰化酰化，分配绝对构型Illisimonin的总合成渗透
6. Determination of the Absolute Configuration ofβ-Chiral Primary Alcohols Using the CompetingEnantioselective Conversion Method [O] . Alexander S. Burns, Alexander J. Wagner, Jennifer L. Fulton, -1

机译：绝对构型的确定竞争性β-手性伯醇对映选择性转化法
7. Convenient method for determining the absolute configuration of chiral alcohols with racemic1H NMR anisotropy reagent, M?NP acid: Use of HPLC-CD detector [O] . Yusuke Kasai, Masataka Watanabe, Nobuyuki Harada 2003

机译：用racemp1h NMR各向异性试剂测定手性醇的绝对配置的方便方法，M 2 NP酸：使用HPLC-CD检测器

Convenient Method for Determining the Absolute Configuration of Chiral Alcohols with Racemic ~1H NMR Anisotropy Reagent, MαNP Acid: Use of HPLC-CD Detector

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