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Aqueous compositions comprising a blend of emulsion vinyl copolymer and polyurethane dispersion

机译:包含乳液乙烯基共聚物和聚氨酯分散体的共混物的水性组合物

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摘要

The present invention provides an aqueous composition comprising: a) a plurality of polymer particles (A) comprising one or more copolymer, pA, having a glass transition temperature, Tg, of 20°C or higher, as measured by differential scanning calorimetry, DSC; b) a plurality of polymer particles (B) in aqueous dispersion comprising one or more polyurethane copolymer, pB, comprising at least 40 wt%, based on the weight of polyurethane solids, of: (i) a first polyol having a molecular weight of at least 850, wherein the first polyol is a polyether polyol, or (ii) a second polyol chosen from a polyester, a polycaprolactam, a polycarbonate and a combination thereof, wherein the second polyol has a molecular weight of at least 1,500, or (iii) a combination of one or more first polyol and one or more second polyol; and c) one or more additive to improve film formation chosen from: a coalescent having a normal boiling point of 150°C to no greater than 300°C present in an amount of at least 4%, based on the total weight of solids of the copolymers pA and pB.
机译:本发明提供了一种水性组合物,其包含:a)通过差示扫描量热法DSC测量的包含一种或多种玻璃化转变温度Tg为20℃或更高的共聚物pA的多个聚合物颗粒(A)。 ; b)在水分散体中的多个聚合物颗粒(B),包括一种或多种聚氨酯共聚物pB,基于聚氨酯固体的重量计,该共聚物包含至少40 wt%的:(i)分子量为至少850,其中第一多元醇是聚醚多元醇,或(ii)选自聚酯,聚己内酰胺,聚碳酸酯及其组合的第二多元醇,其中第二多元醇的分子量至少为1,500,或( iii)一种或多种第一多元醇和一种或多种第二多元醇的组合; c)一种或多种改善成膜的添加剂,选自:沸点在150°C至300°C以下的聚结剂,其含量至少为固体总重量的4%。共聚物pA和pB。

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