High-temperature electrical transport properties of buckypapers composed of doped single-walled carbon nanotubes

摘要

Data on temperature-dependent electrical resistance of buckypaper flakes are presented in this paper. The buckypapers are composed of ropes of aligned single-walled carbon nanotubes doped with HNO_3, which are treated as mixed systems with their properties being dependent on the treatment performed. The measurements cover rather wide temperature range from 300 up to 900 K. In case of untreated samples, curves with two well-defined activation energies are seen, which are discussed in terms of different DC conductivity mechanisms, with a great attention paid to the parallel metal-semiconductor system. In turn, in heat-treated samples the resistance is found nearly temperature-independent except for the significant peak centered at about 600-650 K. Observed characteristics are also fitted using the parallel model, although with a less accuracy suggesting influence of another conductivity mechanisms. At any rate, the resistance peak is possibly related to the metalon-metal transition observed in disordered solids.