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Enhanced anode performance of micro/meso-porous reduced graphene oxide prepared from carbide-derived carbon for energy storage devices

机译:由碳化物衍生的碳制得的用于储能装置的微孔/中孔还原石墨烯的阳极性能得到增强

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摘要

Micro/meso-porous reduced graphite oxide (MMRGO) nanosheets were produced using precursor carbide-derived carbon (CDC), which was produced at a high temperature of 1200 degrees C, through a massive wet chemistry synthetic route involving graphite oxidation and microwave reduction. X-ray diffraction (XRD) and transmission electron microscopy (TEM) show that the MMRGO nanosheets were fabricated with 2-3 layers and ripple-like corrugations. N-2 sorption isotherms confirmed that micro/meso-pores coexisted in the RGO sample from CDC. In the anode application of Li-ion batteries, this RGO sample had an enhanced capacity performance at the 0.1 C rate and 1 C rate, with similar to 1200 mAh g(-1) at the 100th cycle and similar to 1000 mAh g(-1) at the 200th cycle, respectively. Crown Copyright (C) 2015 Published by Elsevier Ltd. All rights reserved.
机译:使用前驱物碳化物衍生的碳(CDC)通过包括石墨氧化和微波还原的大规模湿化学合成路线,使用前驱物碳化物衍生的碳(CDC)制备了微孔/中孔还原氧化石墨(MMRGO)纳米片。 X射线衍射(XRD)和透射电子显微镜(TEM)表明,MMRGO纳米片的制造具有2-3层和波纹状波纹。 N-2吸附等温线证实在CDC的RGO样品中微孔/中孔共存。在锂离子电池的负极应用中,该RGO样品在0.1 C和1 C速率下具有增强的容量性能,在第100个循环时类似于1200 mAh g(-1),而对于1000 mAh g(- 1)分别在第200个周期。 Crown版权所有(C)2015,由Elsevier Ltd.发行。保留所有权利。

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