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Partial nitrification of wastewater from an aminoplastic resin producing factory

机译:氨基塑料树脂生产厂废水的部分硝化

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Nitrification via nitrite was studied in two aerobic reactors treating wastewater from an aminoplastic resin producing factory at HRT varying between 1.37- 1.89 and 2.45-3.63 days. Both reactors were fed with concentrations of 366, 450, 1099 and 1899 mg N-NH4+/L. In general in the reactor operated at a lower HRT, the nitritation percentage decreased from 87.2 to 21.6%, while the nitratation percentage remained always lower than 2.5% (except in the last period) when the ammonium concentration was increased. This behaviour could be due to the inhibition of the ammonium and nitrite oxidation produced by high free ammonia concentrations up to 179.3 mg N-NH3/L. In the reactor operated at a higher HRT, the nitritation percentage decreased and the nitratation percentage increased from 88.6 to 39.6% and from 0.65 to 35.7%, respectively, due to an increase of the dissolved oxygen concentration from 0.76 to 1.02 mg O-2/L. However, when ammonium was fed at a concentration of 1898.7 mg N-NH4+/L, the nitritation increased and the nitratation decreased, probably as a result of the accumulation of free ammonia up to 2.04 mg N-NH3/L, meaning that nitrite oxidizers were inhibited. Nitrite build-up was observed after each modification of ammonium concentration in the feed.
机译:在两个好氧反应器中研究了亚硝酸盐的硝化作用,该反应器处理HRT氨基塑料树脂生产厂的废水,时间在1.37-1.89到2.45-3.63天之间。向两个反应器中进料的浓度分别为366、450、1099和1899 mg N-NH4 + / L。通常,在较低的HRT下运行的反应器中,当铵浓度增加时,硝化百分比从87.2降低到21.6%,而硝化百分比始终保持低于2.5%(最后一个时期除外)。此行为可能是由于抑制了高达179.3 mg N-NH3 / L的高游离氨浓度所产生的铵盐和亚硝酸盐氧化。在较高的HRT下运行的反应器中,由于溶解氧浓度从0.76 mg O-2 /增加到了5.5%,硝化百分比从88.6%增加到39.6%和从0.65%增加到35.7%。 L.但是,当以1898.7 mg N-NH4 + / L的浓度进料铵时,硝化作用增加而硝化作用减少,这可能是由于游离氨累积达到2.04 mg N-NH3 / L所致,这意味着亚硝酸盐氧化剂被抑制。在进料中每次改变铵浓度后,观察到亚硝酸盐积累。

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