Synthesis of a tetrasaccharide substrate of heparanase

Chen JF; Zhou Y; Chen C; Xu WC; Yu B

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Synthesis of a tetrasaccharide substrate of heparanase

机译：乙酰肝素酶四糖底物的合成

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A tetrasaccharide, corresponding to the heparan sulfate heparanase substrate, namely beta-D-GIcA(2S)-(1 -> 4)-alpha-D-GIcN(NS,6S)-(1 -> 4)-beta-D-GIcA-(1 -> 4)-alpha-D-GIcN(NS,6S)-OMe, was synthesized in a convergent manner via coupling of a pair of the disaccharide building blocks as a key step. (C) 2008 Elsevier Ltd. All rights reserved.

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《Carbohydrate research》 |2008年第17期|共10页
作者
Chen JF; Zhou Y; Chen C; Xu WC; Yu B;
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正文语种 eng
中图分类 Q629;
关键词
Heparan sulfate; Synthesis; Heparanase; Glycosylation; Thioglycoside; Trifluoroacetimidate; SULFATE PROTEOGLYCANS; CANCER METASTASIS; PROTECTING GROUPS; BUILDING-BLOCKS; GLYCOSYL DONORS; PART 1; HEPARIN; OLIGOSACCHARIDES; SEQUENCE; PENTASACCHARIDE;

机译：硫酸乙酰肝素;合成;乙酰肝素酶;糖基化;硫代糖苷;三氟乙酰亚氨酸;硫酸盐蛋白聚糖;癌症转移;保护基;砌块;糖基给体;部分1;肝素;寡糖;序列;五磷酸;

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1. Efficient synthesis of a library of heparin tri- and tetrasaccharides relevant to the substrate of heparanase [J] . Peng Xu, Weichang Xu, Yuanwei Dai Organic Chemistry Frontiers . 2014,第4期

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2. Synthesis of a tetrasaccharide substrate of heparanase [J] . Chen JF, Zhou Y, Chen C, Carbohydrate research . 2008,第17期

机译：乙酰肝素酶四糖底物的合成
3. A practical synthesis of capped 4-methylumbelliferyl hyaluronan disaccharides and tetrasaccharides as potential hyaluronidase substrates [J] . Gold H., Munneke S., Dinkelaar J., Carbohydrate research . 2011,第12期

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4. Synthesis of Simple Heparanase Substrates [C] . Pearson. A.G., Kiefel M.J., Ferro V. International Carbohydrate Symposium . 2013

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5. I. Microwave-influenced diversity-oriented synthesis of biologically relevant small and natural-product-like molecules via multicomponent coupling reactions. II. Synthetic studies toward the total synthesis of the repeating tetrasaccharide unit of zwitterionic polysaccharide PS A1. [D] . Santra, Soumava. 2010

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Synthesis of a tetrasaccharide substrate of heparanase

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