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Synthesis and characterization of a novel super-absorbent based on chemically modified pulverized wheat straw and acrylic acid

机译:化学改性的麦秸粉和丙烯酸为基础的新型高吸水剂的合成与表征

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摘要

In order to develop an eco-friendly polymer, the material was prepared from pulverized wheat straw by chemical methods. And a super-absorbent hydrogel has been synthesized with chemically modified pulverized wheat straw (CMPWS) and acrylic acid (AA) in aqueous solution. Factors, such as weight ratio of AA to CMPWS, the amount of initiator and cross-linker, temperature and neutralization degree of AA that influence absorbencies of super-absorbent were investigated. Moreover, the super-absorbent had been proved with expectant polymerization structure and good thermo-stability via IR spectrum and TGA analysis. The morphological features were evidenced by SEM images. The excellent product was obtained with the absorbencies of 417 g/g in distilled water and 45g/g in 0.9 wt% NaCl solution.
机译:为了开发生态友好的聚合物,该材料是通过化学方法由粉碎的麦秸秆制备的。并以水溶液中化学修饰的麦草粉(CMPWS)和丙烯酸(AA)为原料合成了高吸收性水凝胶。研究了AA与CMPWS的重量比,引发剂和交联剂的用量,AA的温度和中和度等因素对高吸收剂吸收性能的影响。此外,通过IR光谱和TGA分析证明了该高吸收剂具有预期的聚合结构和良好的热稳定性。 SEM图像证实了其形态特征。获得了优异的产品,在蒸馏水中的吸光度为417 g / g,在0.9 wt%的NaCl溶液中的吸光度为45g / g。

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