Synthesis,crystal structure determination,spectroscopic and electrochemical studies of trans-[Ru(PPh_3)_2(bbpH_2)CllCl centre dot CHC1_3 H_20 (bbpH_2=2,6-bis(benzimidazolyl) pyridine) - an infinite double columnar supramolecule in the solid state

摘要

The synthesis,crystal structure,redox and spectroscopic properties of trans-[Ru(bbpH_2)(PPh_3)_2Cl]Cl are reported.In the crystalline solvate trans-[Ru(bbpH_2)(PPh_3)_(2c)Cl]Cl centre dot CHCl_3 centre dot H_2O,the molecular components are connected by strong intermolecular hydrogen bonding to form an infinite double column.